Abstract: A study has been made of the interaction of complexes of palladium containing aromatic ligands with various types of supports, and the possibility of strong adsorption of these complexes on the surface of carbon materials has been demonstrated. The catalytic properties of these supported systems are highly dependent on the site of localization of the palladium center. In the reaction of vinyl exchange, the anchored complexes manifest high activity if the ligands that are present enable the palladium atom to be positioned at a certain distance from the substrate surface. At the same time, close contact between the active center and the support in the adsorption of planar phenanthroline complexes leads to a drop in their chemical activity in this process.

Cite: Keterling A.A. , Lisitsyn A.S. , Likholobov V.A. , Gallʹ A.A. , Trachum A.S.
Adsorption of Complexes with Aromatic Ligands on Carbon Supports as a Means for Obtaining Heterogenized Catalysts
Kinetics and Catalysis. 1991. V.31. N6 pt 2. P.1273-1277. WOS РИНЦ

Original: Кетерлинг А.А. , Лисицын А.С. , Лихолобов В.А. , Галль А.А. , Трачум А.С.
Адсорбция комплексов с ароматическими лигандами на углеродных носителях как способ получения гетерогенизированных катализаторов
Кинетика и катализ. 1990. Т.31. №6. С.1453-1457. РИНЦ ANCAN

Dates:

Submitted:	Jul 28, 1989
Published print:	Feb 1, 1991

Identifiers:

Web of science:	WOS:A1990FY99400008
Elibrary:	31094875

Citing:

DB	Citing
Web of science	6