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The Effect of Active Site Composition and Support Structure in Supported Catalysts on the Nascent Morphology of Polyethylene Full article

Journal Makromolekulare Chemie up to 1993, continued as Macromolecular Chemistry and Physics
ISSN: 0025-116X
Output data Year: 1988, Volume: 189, Number: 8, Pages: 1739-1753 Pages count : 15 DOI: 10.1002/macp.1988.021890801
Authors Semikolenova Nina V. 1 , Nesterov Gennadii A. 1 , Zakharov Vladimir A. 1 , Krjukova Galina N. 1 , Ivanov Vyacheslav P. 1 , Gol'denberg Grigorii I. 2
Affiliations
1 Institute of Catalysis, Novosibirsk 630090, USSR
2 Special Catalyst Designing Bureau, Ministry of Chemical Industry, Novosibirsk, USSR

Abstract: The formation process and morphology of polyethylene (PE) produced by the non-porous catalyst species tufa- and kaoline-supported Cr(C5H5)2, Zr(BH4)4 and TiCl4 were studied by scanning electron microscopy (SEM) and X-ray photoelectron spectroscopy (XPS). The PE morphology was found to depend upon the catalyst active component composition, the polymer yield and the morphology of the support. A quantitative estimation of the PE coverage of the catalyst particles was made.
Cite: Semikolenova N.V. , Nesterov G.A. , Zakharov V.A. , Krjukova G.N. , Ivanov V.P. , Gol'denberg G.I.
The Effect of Active Site Composition and Support Structure in Supported Catalysts on the Nascent Morphology of Polyethylene
Makromolekulare Chemie up to 1993, continued as Macromolecular Chemistry and Physics. 1988. V.189. N8. P.1739-1753. DOI: 10.1002/macp.1988.021890801 WOS РИНЦ ANCAN OpenAlex
Dates:
Submitted: Jun 23, 1987
Published print: Aug 1, 1988
Published online: Mar 12, 2003
Identifiers:
Web of science: WOS:A1988P957500001
Elibrary: 23410476
Chemical Abstracts: 1988:571008
Chemical Abstracts (print): 109:171008
OpenAlex: W1809180508
Citing:
DB Citing
Web of science 8
Elibrary 8
OpenAlex 9
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