New Adsorbents of Methanol for the Intensification of Methanol Synthesis | Sciact - CRIS-system of Boreskov Institute of Catalysis

New Adsorbents of Methanol for the Intensification of Methanol Synthesis Full article

Journal

Reaction Kinetics, Mechanisms and Catalysis
ISSN: 1878-5190 , E-ISSN: 1878-5204

Output data

Year: 2012, Volume: 105, Pages: 391-400 Pages count : 10 DOI: 10.1007/s11144-011-0379-z

Tags

Adsorption, Composites, Intensification, Methanol synthesis, Salt in porous matrix, Separations

Authors

Gordeeva L.G. ¹ , Khassin A.A. ¹ , Chermashentseva G.K. ¹ , Krieger T.A. ¹

Affiliations

1	Boreskov Institute of Catalysis, Ac. Lavrentiev av 5, Novosibirsk 630090, Russia

Novel composite adsorbents Ca(NO3)2)/SiO2, LiBr/SiO2 and CaCl2/SiO2 have been intently designed for shifting the equilibrium of methanol synthesis by methanol removal from the reaction mixture. Testing of these composites in a lab-scale tubular flow reactor at the initial mixture composition CO/CO2/N2/H2 = 30.0/2.0/3.2/64.8, total pressure P = 2 MPa and temperature T = 473 K has shown their encouraging potential for this application. The former composite efficiently adsorbs methanol from the gaseous mixture under lab-scale operating conditions of methanol synthesis and demonstrates good thermal stability. It can be recommended for further testing.

Gordeeva L.G. , Khassin A.A. , Chermashentseva G.K. , Krieger T.A.
New Adsorbents of Methanol for the Intensification of Methanol Synthesis
Reaction Kinetics, Mechanisms and Catalysis. 2012. V.105. P.391-400. DOI: 10.1007/s11144-011-0379-z WOS Scopus РИНЦ ANCAN OpenAlex

Submitted:	Jan 21, 2011
Accepted:	Sep 18, 2011
Published online:	Oct 7, 2011
Published print:	Apr 1, 2012

Web of science:	WOS:000303536800015
Scopus:	2-s2.0-84905251078
Elibrary:	23960428
Chemical Abstracts:	2012:330218
Chemical Abstracts (print):	156:392533
OpenAlex:	W2105149370

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