Synthesis, Properties and Structure of Binuclear Anionic "Mo(V) hydroxide", [Mo2O4(OH)4(H2O2]2- Full article
| Journal |
Polyhedron
ISSN: 0277-5387 |
||
|---|---|---|---|
| Output data | Year: 1994, Volume: 13, Number: 3, Pages: 505-512 Pages count : 8 DOI: 10.1016/S0277-5387(00)81667-8 | ||
| Tags | MOLYBDENUM(V) COMPLEXES; HYDROPEROXIDES; OLEFINS; OXALATE; SPECTRA | ||
| Authors |
|
||
| Affiliations |
|
Abstract:
The structure of “molybdenum(V) hydroxide” has been defined. The complex was obtained from MoOd2- molybdate anion reduction with hydrazine-hydrate in aqueous solution. This compound is assigned the formula
(N2H5)2[Moz~-O)202(OH).,(H20)2], dihydrazonium[di-y-oxo-bis-(aquadihydroxooxomolybdate~]. The product similar in structure as that obtained on MoOh2- reduction with NaBH, and on (NH,),MoOCl, hydrolysis. Upon dissolving molybdenum(V) hydroxide in oxalic or tartaric acid solutions the diamagnetic complexes are obtained and characterized by means of IR, NMR and EXAFS spectroscopy.
Cite:
Startsev A.N.
, Klimov O.V.
, Shkuropat S.A.
, Fedotov M.A.
, Degtyarev S.P.
, Kochubey D.I.
Synthesis, Properties and Structure of Binuclear Anionic "Mo(V) hydroxide", [Mo2O4(OH)4(H2O2]2-
Polyhedron. 1994. V.13. N3. P.505-512. DOI: 10.1016/S0277-5387(00)81667-8 WOS Scopus РИНЦ ANCAN OpenAlex
Synthesis, Properties and Structure of Binuclear Anionic "Mo(V) hydroxide", [Mo2O4(OH)4(H2O2]2-
Polyhedron. 1994. V.13. N3. P.505-512. DOI: 10.1016/S0277-5387(00)81667-8 WOS Scopus РИНЦ ANCAN OpenAlex
Dates:
| Submitted: | Feb 22, 1993 |
| Accepted: | Aug 18, 1993 |
| Published print: | Feb 1, 1994 |
| Published online: | Apr 10, 2001 |
Identifiers:
| Web of science: | WOS:A1994MW96500027 |
| Scopus: | 2-s2.0-0038591255 |
| Elibrary: | 31119991 |
| Chemical Abstracts: | 1994:259892 |
| Chemical Abstracts (print): | 120:259892 |
| OpenAlex: | W2079376813 |