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Effect of Calcination Temperature on the Surface Composition of Mo-Fe Catalysts for Methanol Oxidation Full article

Journal Reaction Kinetics and Catalysis Letters
ISSN: 0133-1736 , E-ISSN: 1588-2837
Output data Year: 1986, Volume: 30, Number: 1, Pages: 129-135 Pages count : 7 DOI: 10.1007/BF02068156
Tags Oxidation; Iron; Solid Solution; Catalysis; Catalytic Activity
Authors Popov B.I. 1 , Pashis A.V. 1 , Shkuratova L.N. 1
Affiliations
1 Institute of Catalysis, Novosibirsk 630090, USSR

Abstract: XPS studies have revealed a decrease in the concentration of iron atoms on the surface of Mo−Fe catalysts with increasing calcination temperature. From a comparison of chemical analysis and XPS data the Mo/Fe ratios on the surface of catalyst samples at various calcination temperatures have been determined. Comparing the above data with changes in the catalytic activity of the samples examined in methanol oxidation, the conclusion has been made that the active component of the catalysts is a solid solution of molybdenum oxide in ferric molybdate.
Cite: Popov B.I. , Pashis A.V. , Shkuratova L.N.
Effect of Calcination Temperature on the Surface Composition of Mo-Fe Catalysts for Methanol Oxidation
Reaction Kinetics and Catalysis Letters. 1986. V.30. N1. P.129-135. DOI: 10.1007/BF02068156 WOS Scopus РИНЦ ANCAN OpenAlex
Dates:
Submitted: Aug 30, 1984
Accepted: Jan 7, 1985
Published print: Mar 1, 1986
Identifiers:
Web of science: WOS:A1986C572500018
Scopus: 2-s2.0-0011351425
Elibrary: 30814284
Chemical Abstracts: 1986:430729
Chemical Abstracts (print): 105:30729
OpenAlex: W2072360503
Citing:
DB Citing
Web of science 16
Scopus 16
Elibrary 15
OpenAlex 15
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