Kinetic Study of Alcohol-Catalyzed Substitution of tris(Dibenzoylmethanato) Fe(III) Ligands by Acetylacetone Full article
| Journal |
Reaction Kinetics and Catalysis Letters
ISSN: 0133-1736 , E-ISSN: 1588-2837 |
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| Output data | Year: 1986, Volume: 32, Number: 2, Pages: 263-267 Pages count : 5 DOI: 10.1007/BF02068321 | ||
| Tags | Physical Chemistry; Catalysis; Phenyl; Exchange Reaction; Kinetic Study | ||
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Abstract:
It is shown that substitution of the CH3 group by phenyl group in the β-diketonato ring does not change the general mechanism of the exchange reaction. The reaction rate fall observed may be due either to a greater stability of tris(di-benzoylmethanato) Fe(III) (Fe(dbm) compared to tris(benzoylacetonato) Fe(III) (Fe(ba)3) or to a decrease in the stability of the Fe(dbm)3·ROH complex, which is a precursor of the rate-determining step, in comparison with Fe(ba)3·ROH.
Cite:
Ivanchenko V.A.
, Nekipelov V.M.
Kinetic Study of Alcohol-Catalyzed Substitution of tris(Dibenzoylmethanato) Fe(III) Ligands by Acetylacetone
Reaction Kinetics and Catalysis Letters. 1986. V.32. N2. P.263-267. DOI: 10.1007/BF02068321 WOS Scopus РИНЦ ANCAN OpenAlex
Kinetic Study of Alcohol-Catalyzed Substitution of tris(Dibenzoylmethanato) Fe(III) Ligands by Acetylacetone
Reaction Kinetics and Catalysis Letters. 1986. V.32. N2. P.263-267. DOI: 10.1007/BF02068321 WOS Scopus РИНЦ ANCAN OpenAlex
Dates:
| Submitted: | Jul 2, 1985 |
| Accepted: | Jan 8, 1986 |
| Published print: | Sep 1, 1986 |
Identifiers:
| Web of science: | WOS:A1986H257200003 |
| Scopus: | 2-s2.0-34250126431 |
| Elibrary: | 30844228 |
| Chemical Abstracts: | 1988:112669 |
| Chemical Abstracts (print): | 108:112669 |
| OpenAlex: | W2576270120 |