ESR Study of Ordered Ti(III) Clusters in Frozen Solutions Научная публикация
| Журнал |
Reaction Kinetics and Catalysis Letters
ISSN: 0133-1736 , E-ISSN: 1588-2837 |
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| Вых. Данные | Год: 1994, Том: 52, Номер: 2, Страницы: 261-267 Страниц : 7 DOI: 10.1007/BF02067797 | ||
| Ключевые слова | Chloride; Titanium; Physical Chemistry; Catalysis; Tetrahedral Coordination | ||
| Авторы |
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| Организации |
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Реферат:
The ESR spectrum of exchange-coupled Ti3+ ions of g⊥< g‖ ≃ ge has been observed in dissolution products of metallic titanium in HCl, evidencing the formation of chloride clusters of mutually ordered Ti3+ ions in dz2-ground state in distorted tetrahedral coordination. The cooperative Jahn-Teller effect (CJTE) defines orbital ordering of the d1 of Ti3+ ions in the cluster.
Библиографическая ссылка:
Altynnikov A.A.
, Kalinkina O.V.
, Anufrienko V.F.
, Shubin A.A.
, Vossel S.V.
, Zakharov V.V.
, Bulgakov N.N.
ESR Study of Ordered Ti(III) Clusters in Frozen Solutions
Reaction Kinetics and Catalysis Letters. 1994. V.52. N2. P.261-267. DOI: 10.1007/BF02067797 WOS Scopus РИНЦ CAPlusCA OpenAlex
ESR Study of Ordered Ti(III) Clusters in Frozen Solutions
Reaction Kinetics and Catalysis Letters. 1994. V.52. N2. P.261-267. DOI: 10.1007/BF02067797 WOS Scopus РИНЦ CAPlusCA OpenAlex
Даты:
| Поступила в редакцию: | 10 сент. 1993 г. |
| Принята к публикации: | 28 окт. 1993 г. |
| Опубликована в печати: | 1 июн. 1994 г. |
Идентификаторы БД:
| Web of science: | WOS:A1994QA67700004 |
| Scopus: | 2-s2.0-0028460037 |
| РИНЦ: | 31171230 |
| Chemical Abstracts: | 1995:264468 |
| Chemical Abstracts (print): | 122:121435 |
| OpenAlex: | W1987162691 |