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15N NMR Studies of the NO-NH3-O2 Reaction over ZSM-5 Type Zeolites and Vanadia Supported Catalysts Full article

Journal Reaction Kinetics and Catalysis Letters
ISSN: 0133-1736 , E-ISSN: 1588-2837
Output data Year: 1995, Volume: 54, Number: 2, Pages: 419-426 Pages count : 8 DOI: 10.1007/BF02071035
Tags Zeolite; Nuclear Magnetic Resonance; Vanadia; Nuclear Magnetic Resonance Spectrum; Disproportionation
Authors Filimonova S.V. 1 , Mastikhin V.M. 1
Affiliations
1 Boreskov Institute of Catalysis, Novosibirsk 630090, Russia

Funding (1)

1 Russian Foundation for Basic Research 93-03-4772

Abstract: 15N nuclear magnetic resonance spectra produced by adsorption of NO together with O2 and NH3 on H-ZSM-5 and V2O5/Al2O3 catalysts have been examined. Several surface species and reaction intermediates have been identified by their characteristic 15N NMR spectra. The intermediate complexes between the products of disproportionation and partial oxidation of NO, on one hand, and ammonia, on the other hand, were found to be formed in the reaction. On V2O5/Al2O3 catalyst the reaction proceeds more rapidly compared with ZSM-5 but some details of the mechanism are similar for both catalysts.
Cite: Filimonova S.V. , Mastikhin V.M.
15N NMR Studies of the NO-NH3-O2 Reaction over ZSM-5 Type Zeolites and Vanadia Supported Catalysts
Reaction Kinetics and Catalysis Letters. 1995. V.54. N2. P.419-426. DOI: 10.1007/BF02071035 WOS Scopus РИНЦ ANCAN OpenAlex
Dates:
Submitted: Sep 27, 1994
Accepted: Oct 31, 1994
Published print: Feb 1, 1995
Identifiers:
Web of science: WOS:A1995QY59400023
Scopus: 2-s2.0-34249760532
Elibrary: 30835202
Chemical Abstracts: 1995:590658
Chemical Abstracts (print): 123:207548
OpenAlex: W2314567117
Citing: Пока нет цитирований
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