Structure of Polynuclear Palladium(II) Hydroxocomplexes Formed upon Alkaline Hydrolysis of Palladium(II) Chloride Complexes Full article
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Russian Chemical Bulletin
ISSN: 1066-5285 , E-ISSN: 1573-9171 |
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| Output data | Year: 1995, Volume: 44, Number: 10, Pages: 1822-1826 Pages count : 5 DOI: 10.1007/BF00707203 | ||
| Tags | EXAFS, hydrolysis, palladium(ii), polynuclear complexes, SAXS, size distribution of particles, TEM | ||
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Abstract:
The structure of polynuclear PdII hydroxocomplexes (PHC) formed as a result of alkaline hydrolysis of PdII chloride complexes was studied by EXAFS, SAXS, and TEM methods. It is established that in aqueous solutions a hydroxocomplex particle is a filament curled into a ball containing about 100 Pd atoms. The filament consists of planar coordination squares of PdO4 units linkedvia one or two oxygen bridges of different geometry. Aging of samples results in an increase in the number of single bridging ligands and a decrease in the diameter of particles. Interatomic distances around palladium atoms were determined.
Cite:
Troitskii S.Y.
, Chuvilin A.L.
, Kochubey D.I.
, Novgorodov B.N.
, Kolomiichuk V.N.
, Likholobov V.A.
Structure of Polynuclear Palladium(II) Hydroxocomplexes Formed upon Alkaline Hydrolysis of Palladium(II) Chloride Complexes
Russian Chemical Bulletin. 1995. V.44. N10. P.1822-1826. DOI: 10.1007/BF00707203 WOS Scopus РИНЦ OpenAlex
Structure of Polynuclear Palladium(II) Hydroxocomplexes Formed upon Alkaline Hydrolysis of Palladium(II) Chloride Complexes
Russian Chemical Bulletin. 1995. V.44. N10. P.1822-1826. DOI: 10.1007/BF00707203 WOS Scopus РИНЦ OpenAlex
Original:
Троицкий С.Ю.
, Чувилин А.Л.
, Кочубей Д.И.
, Новгородов Б.Н.
, Коломийчук В.Н.
, Лихолобов В.А.
Структура полиядерных гидроксокомплексов палладия(II), образующихся при щелочном гидролизе его хлоридных комплексов
Известия Академии наук. Серия химическая. 1995. №10. С.1901-1905. РИНЦ ANCAN
Структура полиядерных гидроксокомплексов палладия(II), образующихся при щелочном гидролизе его хлоридных комплексов
Известия Академии наук. Серия химическая. 1995. №10. С.1901-1905. РИНЦ ANCAN
Dates:
| Submitted: | Apr 25, 1995 |
| Published print: | Oct 1, 1995 |
Identifiers:
| Web of science: | WOS:A1995TQ44100004 |
| Scopus: | 2-s2.0-77955438371 |
| Elibrary: | 26582002 |
| OpenAlex: | W269028062 |