Anthraquinones Formation on Zeolites with BEA Structure Научная публикация
| Конференция |
10th International Zeolite Conference 17-22 июл. 1994 , Garmisch-Partenkirchen |
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| Сборник | Zeolites and Related Microporous Materials: State of the Art 1994 - Proceedings of the 10th International Zeolite Conference, Garmisch-Partenkirchen, Germany, 17-22 July 1994 Сборник, 1994. 2366 c. ISBN 978-0-444-81847-8. |
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| Журнал |
Studies in Surface Science and Catalysis
ISSN: 0167-2991 |
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| Вых. Данные | Год: 1994, Том: 84, Страницы: 1905-1912 Страниц : 8 DOI: 10.1016/S0167-2991(08)63748-9 | ||||||
| Авторы |
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| Организации |
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Реферат:
Zeolites with BEA structure are in focus mainly in the field of conversion of hydrocarbons. However, their unique physico-chemical properties let to suppose that these systems can be successfully used in reactions of organic synthesis. Such zeolites can be used as catalysts for the synthesis of large organic molecules. The interaction of phthalic anhydride with aromatic hydrocarbons is a subject for investigation, both for science purposes and for industrial applications. The use of zeolites in this reaction is an example of the acylation of aromatics on solid-acid catalysts; on the other hand, such a study creates the possibilities of developing more appropriate technology for the production of anthraquinone compounds. This chapter presents experimental material on the investigation of catalytic properties of zeolites with BEA structure in anthraquinones formation. The chapter presents a study of the interaction of both initial reagents and reaction products with acid sites of zeolite using IR technique. On the base of the obtained data, a mechanism of formation of reaction products was proposed. The catalytic properties of zeolite with BEA structure were examined in the reaction in the range of 225–500°C. Increasing the reaction temperature can cause the decomposition of not only anthraquinone molecules but also of phthalic anhydride and benzoylbenzoic acid, which can lose CO and CO2 giving benzophenone, biphenyl, and 9-fluorenone as reaction products.
Библиографическая ссылка:
Kikhtyanin O.V.
, Ione K.G.
, Snytnikova G.P.
, Malysheva L.V.
, Toktarev A.V.
, Paukshtis E.A.
, Spichtinger R.
, Schüth F.
, Unger K.K.
Anthraquinones Formation on Zeolites with BEA Structure
В сборнике Zeolites and Related Microporous Materials: State of the Art 1994 - Proceedings of the 10th International Zeolite Conference, Garmisch-Partenkirchen, Germany, 17-22 July 1994. 1994. – C.1905-1912. – ISBN 978-0-444-81847-8. DOI: 10.1016/S0167-2991(08)63748-9 WOS Scopus РИНЦ CAPlusCA OpenAlex
Anthraquinones Formation on Zeolites with BEA Structure
В сборнике Zeolites and Related Microporous Materials: State of the Art 1994 - Proceedings of the 10th International Zeolite Conference, Garmisch-Partenkirchen, Germany, 17-22 July 1994. 1994. – C.1905-1912. – ISBN 978-0-444-81847-8. DOI: 10.1016/S0167-2991(08)63748-9 WOS Scopus РИНЦ CAPlusCA OpenAlex
Даты:
| Опубликована в печати: | 1 янв. 1994 г. |
| Опубликована online: | 23 мая 2008 г. |
Идентификаторы БД:
| Web of science: | WOS:A1994BD02E00235 |
| Scopus: | 2-s2.0-0000699072 |
| РИНЦ: | 30813501 |
| Chemical Abstracts: | 1995:211442 |
| Chemical Abstracts (print): | 122:31058 |
| OpenAlex: | W799394077 |