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HREELS/TDS Identification of Intermediates in The Low-Temperature H2+O2, NO+H2, NH3+O2 Reactions on Pt(111) Surface Научная публикация

Конференция New Frontiers in Catalysis : 10th International Congress on Catalysis
19-24 июл. 1992 , Budapest
Сборник New Frontiers in Catalysis : Proceedings of the 10th International Congress on Catalysis, Budapest, 19-24 July 1992
Сборник, Elsevier. Amsterdam-London-New York-Tokyo.1993. 2859 c.
Журнал Studies in Surface Science and Catalysis
ISSN: 0167-2991
Вых. Данные Год: 1993, Том: 75, Страницы: 1587-1590 Страниц : 4 DOI: 10.1016/S0167-2991(08)64486-9
Авторы Gorodetskii V.V. 1 , Smirnov M.Yu. 1 , Cholach A.R. 1
Организации
1 Institute of Catalysis, Russian Academy of Sciences, Siberian Division, Novosibirsk 630090, Russia

Реферат: There is a possibility of the formation of different products during NO reduction with hydrogen and NH3 oxidation depending on the conditions and the metals used. The character of the NO adsorbed state (molecular or dissociative) determines the formation of the key product (NH3 or N2). The activity of Pt toward breaking the N–O bond is very sensitive to the surface structure. The study of low-temperature oxidative catalysis described in the chapter establishes the mechanisms of the reactions proceeding with the participation of the reactants in the molecularly adsorbed states. In the study described in the chapter, high resolution electron energy loss spectroscopy (HREELS) and thermal desorption spectroscopy (TDS) were used for the study of the low-temperature adsorption of H2, O2, NO, and NH3 and the H2 + O2, NO + H2, and NH3 + O2 reactions on the Pt(III) surface. Experiments were carried out by VG ADES-400 spectrometer, and the monochromatic electron beam with a kinetic energy of 2.5 eV and resolution of 10 meV (80 cm−1) was used.
Библиографическая ссылка: Gorodetskii V.V. , Smirnov M.Y. , Cholach A.R.
HREELS/TDS Identification of Intermediates in The Low-Temperature H2+O2, NO+H2, NH3+O2 Reactions on Pt(111) Surface
В сборнике New Frontiers in Catalysis : Proceedings of the 10th International Congress on Catalysis, Budapest, 19-24 July 1992. – Elsevier., 1993. – Т.1-3. – C.1587-1590. DOI: 10.1016/S0167-2991(08)64486-9 WOS WOS Scopus РИНЦ CAPlusCA OpenAlex
Даты:
Опубликована в печати: 1 янв. 1993 г.
Опубликована online: 3 июн. 2008 г.
Идентификаторы БД:
Web of science: WOS:A1993MK93200064 | WOS:A1993BZ35J00064
Scopus: 2-s2.0-0343187805
РИНЦ: 29830765
Chemical Abstracts: 1993:679849
Chemical Abstracts (print): 119:279849
OpenAlex: W1123167568
Цитирование в БД:
БД Цитирований
Scopus 9
РИНЦ 3
OpenAlex 6
Альметрики: