Interaction of Molecular Nitrogen with Alkali Metals. Communication 1. The Electronic Structure of the Complexes LiN2 and NaN2 | Sciact - CRIS-system of Boreskov Institute of Catalysis

Interaction of Molecular Nitrogen with Alkali Metals. Communication 1. The Electronic Structure of the Complexes LiN2 and NaN2 Full article

Journal

Russian Chemical Bulletin
ISSN: 1066-5285 , E-ISSN: 1573-9171

Output data

Year: 1975, Volume: 24, Number: 6, Pages: 1173-1175 Pages count : 3 DOI: 10.1007/BF00922040

Tags

Nitrogen; Activation Energy; Negative Charge; Alkali Metal; Metal Atom

Authors

Avdeev V.I. ¹ , Borisov Y.A. ² , Bochvar D.A. ² , Bulgakov N.N. ¹ , Zakharov I.I. ¹

Affiliations

1	Institute of Catalysis, Siberian Branch of the Academy of Sciences of the USSR, Novosibirsk
2	Institute of Heteroorganic Compounds, Academy of Sciences of the USSR, Moscow

Conclusions: 1. According to the data of calculations, the addition of an N2 molecule to Li and Na atoms occurs without activation energy, and the complexes formed have a triangular equilibrium configuration with symmetry C2v. 2. Calculation of the complexes LiN2 and NaN2 predicts a small negative charge on the metal atom.

Avdeev V.I. , Borisov Y.A. , Bochvar D.A. , Bulgakov N.N. , Zakharov I.I.
Interaction of Molecular Nitrogen with Alkali Metals. Communication 1. The Electronic Structure of the Complexes LiN2 and NaN2
Russian Chemical Bulletin. 1975. V.24. N6. P.1173-1175. DOI: 10.1007/BF00922040 WOS Scopus РИНЦ OpenAlex

Авдеев В.И. , Борисов Ю.А. , Бочвар Д.А. , Булгаков Н.Н. , Захаров И.И.
Взаимодействие молекулярного азота с щелочными металлами. Сообщение 1. Электронная структура комплексов LiN2 и NaN2
Известия Академии наук. Серия химическая. 1975. №6. С.1271-1273. РИНЦ ANCAN

Submitted:	Jul 22, 1974
Published print:	Jun 1, 1975

Web of science:	WOS:A1975BE94300008
Scopus:	2-s2.0-34250402552
Elibrary:	30840290
OpenAlex:	W2002646199

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