Homogeneous Catalytic Oxidation of Olefins to 1,2-glycol Nitrates in the Presence of Palladium(II) Complexes. Study of the Reaction Mechanism and Kinetics | Sciact - CRIS-system of Boreskov Institute of Catalysis

Homogeneous Catalytic Oxidation of Olefins to 1,2-glycol Nitrates in the Presence of Palladium(II) Complexes. Study of the Reaction Mechanism and Kinetics Full article

Journal

Kinetics and Catalysis
ISSN: 0023-1584 , E-ISSN: 1608-3210

Output data

Year: 1976, Volume: 17, Number: 1, Pages: 112-118 Pages count : 7

Authors

Likholobov V.A. ¹ , Ermakov Y.I. ¹

Affiliations

1	Institute of Catalysis, Academy of Sciences of the USSR, Siberian Branch

Oxidation kinetics of ethene, propene, and 1-butene (esp. ethene) by HNO3 in the presence of PdSO4, Pd(ClO4)2, or Pd(NO3)2 were studied at 0 and ∼25°; the product from ethene was O2NOCH2CH2ONO2. The reaction with ethene took place via π-complex formation; the active catalyst species was [Pd(H2O)3(NO2)]+. The H2O-D2O (solvent) rate ratio was ∼1, owing to the absence of O-H bond breaking in the limiting stage of the reaction.

Likholobov V.A. , Ermakov Y.I.
Homogeneous Catalytic Oxidation of Olefins to 1,2-glycol Nitrates in the Presence of Palladium(II) Complexes. Study of the Reaction Mechanism and Kinetics
Kinetics and Catalysis. 1976. V.17. N1. P.112-118. WOS РИНЦ

Лихолобов В.А. , Ермаков Ю.И.
Гомогенное каталитическое окисление олефинов в нитраты 1,2-гликолей в присутствии комплексов палладия (II). Изучение механизма и кинетики реакции
Кинетика и катализ. 1976. Т.17. №1. С.133-140. РИНЦ ANCAN

Submitted:

Jun 17, 1974

Web of science:	WOS:A1976CG01900020
Elibrary:	30626136

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