Development of New Homogeneous Catalysts for Oxidative Coupling of Aromatic-Compounds Full article
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Kinetics and Catalysis
ISSN: 0023-1584 , E-ISSN: 1608-3210 |
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| Output data | Year: 1977, Volume: 18, Number: 4, Pages: 758-762 Pages count : 5 | ||||
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Abstract:
Oxidative coupling of PhR (R = H, Me, Cl) and of o-xylene and durene using O2 was carried out in the presence of
Pd(OAc)2-H5PMo10V2O40 (I). The reaction was 1st order in O2, 0.9 order in I and 0.4-0.6 order in Pd(II). Addition of Hg(OAc)2 to the reaction mixture increased the rate and selectivity for p-RC6H4C6H4R-p. The rate-determining step was the reoxidation of reduced I, with little effect by R on the rate.
Cite:
Rudenkov A.I.
, Mennenga H.
, Rachkovskaya L.N.
, Matveev K.I.
, Kozhevnikov I.V.
Development of New Homogeneous Catalysts for Oxidative Coupling of Aromatic-Compounds
Kinetics and Catalysis. 1977. V.18. N4. P.758-762. WOS РИНЦ
Development of New Homogeneous Catalysts for Oxidative Coupling of Aromatic-Compounds
Kinetics and Catalysis. 1977. V.18. N4. P.758-762. WOS РИНЦ
Original:
Руденков А.И.
, Менненга Г.У.
, Рачковская Л.Н.
, Матвеев К.И.
, Кожевников И.В.
Исследования по разработке новых гомогенных катализаторов окислительного сочетания ароматических соединений
Кинетика и катализ. 1977. Т.18. №4. С.915-920. РИНЦ ANCAN
Исследования по разработке новых гомогенных катализаторов окислительного сочетания ароматических соединений
Кинетика и катализ. 1977. Т.18. №4. С.915-920. РИНЦ ANCAN
Identifiers:
| Web of science: | WOS:A1977ES67100013 |
| Elibrary: | 30628908 |