Synthesis and Catalytic Properties of Transition-Metal Complexes with Ligands Bound to Surface of Oxide Carriers. 1. Complexes of Palladium with Bound Nitrogen-Containing Ligands | Sciact - CRIS-system of Boreskov Institute of Catalysis

Synthesis and Catalytic Properties of Transition-Metal Complexes with Ligands Bound to Surface of Oxide Carriers. 1. Complexes of Palladium with Bound Nitrogen-Containing Ligands Full article

Journal

Kinetics and Catalysis
ISSN: 0023-1584 , E-ISSN: 1608-3210

Output data

Year: 1977, Volume: 18, Number: 5, Pages: 1060-1065 Pages count : 6

Authors

Semikolenov V.A. ¹ , Likholobov V.A. ¹ , Ermakov Y.I. ¹

Affiliations

1	Institute of Catalysis, Siberian Branch of the USSR Academy of Sciences

N-containing ligands were fixed on a SiO2 surface, e.g., by reaction of SiO2 with Cl3SiCH2CH2CN in toluene at 100-13°; Pd complexes were then formed with these ligands, and the catalytic properties of the complexes were examined in the hydrogenation of 1-hexene (I) and BuOCH:CH2 (II). The Pd complex with the fixed CH2CH2C6H4C(NH2):NOH-p ligand was stable during the hydrogenation; its catalytic activity was 7 times greater with I than with II. These complexes were not as active as Pd itself.

Semikolenov V.A. , Likholobov V.A. , Ermakov Y.I.
Synthesis and Catalytic Properties of Transition-Metal Complexes with Ligands Bound to Surface of Oxide Carriers. 1. Complexes of Palladium with Bound Nitrogen-Containing Ligands
Kinetics and Catalysis. 1977. V.18. N5. P.1060-1065. WOS РИНЦ

Семиколенов В.А. , Лихолобов В.А. , Ермаков Ю.И.
Синтез и каталитические свойства комплексов переходных металлов с лигандами, закрепленными на поверхности окисных носителей. I. Комплексы палладия с азотсодержащими закрепленными лигандами
Кинетика и катализ. 1977. Т.18. №5. С.1294-1300. РИНЦ ANCAN

Submitted:

Jul 19, 1976

Web of science:	WOS:A1977FG47500009
Elibrary:	30628916

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