Preparation and Catalytic Properties of Transition-Metal Complexes Containing Ligands Fixed to Surface of Oxide Supports. 2. Fixed Cobalt Carbonylphosphine Complexes as Catalysts for Selective Hydrogenation of Polyolefins | Sciact - CRIS-system of Boreskov Institute of Catalysis

Preparation and Catalytic Properties of Transition-Metal Complexes Containing Ligands Fixed to Surface of Oxide Supports. 2. Fixed Cobalt Carbonylphosphine Complexes as Catalysts for Selective Hydrogenation of Polyolefins Full article

Journal

Kinetics and Catalysis
ISSN: 0023-1584 , E-ISSN: 1608-3210

Output data

Year: 1978, Volume: 19, Number: 2, Pages: 272-278 Pages count : 7

Authors

Kuznetsov V.L. ¹ , Kuznetsov B.N. ¹ , Ermakov Y.I. ¹

Affiliations

1	Institute of Catalysis

The title catalysts were prepared by treatment of silica gel with (EtO)3SiCH2CH2PR2 (R = Ph, Bu, C6H11), followed by reaction with Co2(CO)8. Catalysts having 1.3-2.6% Co and P/Co ratios of 0.9-1.17 were obtained; IR analysis indicated certain structural differences. The catalytic properties of these complexes in the hydrogenation of cis, trans, trans-1,5,9-cyclododecatriene resembled those of homogeneous Co complexes, especially in the selectivity for monoene formation (≤96%).

Kuznetsov V.L. , Kuznetsov B.N. , Ermakov Y.I.
Preparation and Catalytic Properties of Transition-Metal Complexes Containing Ligands Fixed to Surface of Oxide Supports. 2. Fixed Cobalt Carbonylphosphine Complexes as Catalysts for Selective Hydrogenation of Polyolefins
Kinetics and Catalysis. 1978. V.19. N2. P.272-278. WOS РИНЦ

Кузнецов В.Л. , Кузнецов Б.Н. , Ермаков Ю.И.
Синтез и каталитические свойства комплексов переходных металлов с лигандами, закрепленными на поверхности окисных носителей. II. Закрепленные карбонилфосфиновые комплексы кобальта как катализаторы селективного гидрирования полиолефинов
Кинетика и катализ. 1978. Т.19. №2. С.346-353. РИНЦ ANCAN

Web of science:	WOS:A1978GA33600011
Elibrary:	30628925

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