Participation of Molecular Oxygen in the Formation of Complete Oxidation Products via a Concerted Mechanism Full article
| Journal |
Reaction Kinetics and Catalysis Letters
ISSN: 0133-1736 , E-ISSN: 1588-2837 |
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| Output data | Year: 1977, Volume: 7, Number: 1, Pages: 87-92 Pages count : 6 DOI: 10.1007/BF02068558 | ||
| Tags | Oxidation; Oxygen; Zinc; Catalysis; Isotopic Composition | ||
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Abstract:
A comparison is given between the rate of catalytic reactions and that of decomposition of surface compounds under the influence of molecular oxygen of different isotopic composition in reactions of complete oxidation of n-butane and 1-hexene on zinc oxide and cuprous oxide. It has been shown that the rates of accumulation of products containing heavy oxygen are much smaller than those theoretically expected from the heavy isotope concentration in molecular oxygen. A conclusion is drawn that molecular oxygen is not directly incorporated into the reaction products but promotes decomposition of the surface compounds by oxidizing the surface sites where these compounds are stabilized.
Cite:
Anshiz A.G.
, Sokolovskii V.D.
, Boreskov G.K.
, Boronin A.I.
Participation of Molecular Oxygen in the Formation of Complete Oxidation Products via a Concerted Mechanism
Reaction Kinetics and Catalysis Letters. 1977. V.7. N1. P.87-92. DOI: 10.1007/BF02068558 WOS Scopus РИНЦ ANCAN OpenAlex
Participation of Molecular Oxygen in the Formation of Complete Oxidation Products via a Concerted Mechanism
Reaction Kinetics and Catalysis Letters. 1977. V.7. N1. P.87-92. DOI: 10.1007/BF02068558 WOS Scopus РИНЦ ANCAN OpenAlex
Dates:
| Submitted: | Oct 28, 1976 |
| Accepted: | Jan 25, 1977 |
| Published print: | Jun 1, 1977 |
Identifiers:
| Web of science: | WOS:A1977DN27600015 |
| Scopus: | 2-s2.0-34250291611 |
| Elibrary: | 30858297 |
| Chemical Abstracts: | 1977:474053 |
| Chemical Abstracts (print): | 87:74053 |
| OpenAlex: | W2004258865 |