Transition Metal Catalyzed Asymmetric Oxidation of Sulfides Обзор
| Журнал |
Current Organic Chemistry
ISSN: 1385-2728 , E-ISSN: 1875-5348 |
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| Вых. Данные | Год: 2008, Том: 12, Номер: 5, Страницы: 386-404 Страниц : 19 DOI: 10.2174/138527208783743660 | ||
| Ключевые слова | HIGHLY ENANTIOSELECTIVE OXIDATION; ALKYL ARYL SULFIDES; HYDROGEN-PEROXIDE; KINETIC RESOLUTION; TITANIUM COMPLEXES; CHIRAL SULFOXIDES; IRON COMPLEXES; INHIBITORY-ACTIVITY; LIGANDS; MECHANISM | ||
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Реферат:
In the past two decades, chiral sulfoxides have been finding increasing use, reflecting growing interest both in
convenient auxiliaries in asymmetric synthesis and products with biological properties containing a chiral sulfinyl group. In 1984, groups of Kagan and Modena discovered that titanium(IV) isopropoxide - diethyltartrate based systems (also known as “modified Katsuki-Sharpless reagents”) are capable of asymmetric oxidizing of prochiral sulfides by alkylhydroperoxides. Later, catalytic versions of the titanium tartrate systems were developed (with up to 90 % yield and 90 % ee for certain sulfides) that remain the most applied systems for asymmetric sulfoxidations. However, the low turnover numbers (5-20), complexity and expensiveness of such systems stimulated the search for other transition metal based catalytic systems. This review will cover the progress in transition metal catalyzed asymmetric sulfides oxidations achieved since the discoveries of early 1980s to the present days.
Библиографическая ссылка:
Bryliakov K.P.
, Talsi E.P.
Transition Metal Catalyzed Asymmetric Oxidation of Sulfides
Current Organic Chemistry. 2008. V.12. N5. P.386-404. DOI: 10.2174/138527208783743660 WOS Scopus РИНЦ OpenAlex CAPlusCA
Transition Metal Catalyzed Asymmetric Oxidation of Sulfides
Current Organic Chemistry. 2008. V.12. N5. P.386-404. DOI: 10.2174/138527208783743660 WOS Scopus РИНЦ OpenAlex CAPlusCA
Даты:
| Опубликована в печати: | 1 мар. 2008 г. |
Идентификаторы БД:
| ≡ Web of science: | WOS:000254038500004 |
| ≡ Scopus: | 2-s2.0-42049121685 |
| ≡ РИНЦ: | 13588820 |
| ≡ OpenAlex: | W2951561770 |
| ≡ Chemical Abstracts: | 2008:748065 |
| ≡ Chemical Abstracts (print): | 149:513709 |