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Liquid-Phase Oxidation of Na2S to Na2SO4 on Graphite-Like Carbons Full article

Journal Current Topics in Catalysis
ISSN: 0972-4508
Output data Year: 2010, Volume: 9, Pages: 61-70 Pages count : 10
Tags liquid-phase oxidation, sodium sulfide, carbon catalyst, wet air oxidation
Authors Dobrynkin N.M. 1 , Batygina M.V. 1 , Balʹzhinimaev B.S. 1
Affiliations
1 Boreskov Institute of Catalysis, Siberian Branch of the Russian Academy of Sciences

Abstract: Different types of graphite-like carbons, namely Sibunits, are studied as catalysts in the liquid-phase oxidation of sodium sulfide of high concentrations (28-59 g/l) into sodium sulfate by oxygen, at the temperature range of 90 to 130oC and oxygen pressure of 10 atm. A novel electrochemical mechanism for this liquid phase oxidation by molecular oxygen, which explains most of the experimental data, is suggested.
Cite: Dobrynkin N.M. , Batygina M.V. , Balʹzhinimaev B.S.
Liquid-Phase Oxidation of Na2S to Na2SO4 on Graphite-Like Carbons
Current Topics in Catalysis. 2010. V.9. P.61-70. РИНЦ ANCAN
Identifiers:
Elibrary: 19559312
Chemical Abstracts: 2011:1056071
Chemical Abstracts (print): 155:600483
Citing:
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