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Direct Conversion of Methane on Mo/ZSM-5 Catalysts to Produce Benzene and Hydrogen: Achievements and Perspectives Обзор

Журнал Energy & Environmental Science
ISSN: 1754-5692 , E-ISSN: 1754-5706
Вых. Данные Год: 2008, Том: 1, Номер: 5, Страницы: 526-541 Страниц : 16 DOI: 10.1039/b810981h
Ключевые слова Catalyst selectivity; Methane
Авторы Ismagilov Zinfer R. 1 , Matus Ekaterina V. 1 , Tsikoza Lidia T. 1
Организации
1 Boreskov Institute of catalysis SB RAS, pr. Akademika Lavrentieva, 5, Novosibirsk, 630090, Russia

Реферат: Development of highly effective catalysts for one-stage conversion of light hydrocarbons with high selectivity to valuable products will solve such problems as efficient utilization of natural and oil-associated gases, and environmental protection. Methane dehydroaromatization (DHA) over Mo/ZSM-5 catalysts is a promising process for direct production of valuable aromatic compounds and hydrogen from methane. This review focuses on the range of issues dealing with the effect of catalyst composition, preparation, pretreatment and operation conditions on the physicochemical properties and activities of Mo/ZSM-5 catalysts in DHA reaction. The concepts of the reaction mechanism and the nature of the active molybdenum forms are reviewed. Various aspects of the Mo/ZSM-5 deactivation under reaction conditions and methods of their regeneration are discussed. Some approaches for improvement of the Mo/ZSM-5 performance in DHA reaction are addressed in the review in detail. The perspectives of the methane dehydroaromatization process are also presented.
Библиографическая ссылка: Ismagilov Z.R. , Matus E.V. , Tsikoza L.T.
Direct Conversion of Methane on Mo/ZSM-5 Catalysts to Produce Benzene and Hydrogen: Achievements and Perspectives
Energy & Environmental Science. 2008. V.1. N5. P.526-541. DOI: 10.1039/b810981h WOS Scopus РИНЦ CAPlusCA OpenAlex
Даты:
Поступила в редакцию: 27 июн. 2008 г.
Принята к публикации: 4 авг. 2008 г.
Опубликована online: 28 авг. 2008 г.
Идентификаторы БД:
Web of science: WOS:000263888300002
Scopus: 2-s2.0-70349505457
РИНЦ: 15293294
Chemical Abstracts: 2008:1464444
Chemical Abstracts (print): 151:384775
OpenAlex: W1995532080
Цитирование в БД:
БД Цитирований
Web of science 204
Scopus 228
РИНЦ 227
OpenAlex 242
Альметрики: