H2O2-Based Oxidation of Functionalized Phenols Containing Several Oxidizable Sites to p-Quinones Using a Mesoporous Titanium-Slicate Catalyst | Sciact - CRIS-system of Boreskov Institute of Catalysis

H2O2-Based Oxidation of Functionalized Phenols Containing Several Oxidizable Sites to p-Quinones Using a Mesoporous Titanium-Slicate Catalyst Full article

Journal

Green Chemistry
ISSN: 1463-9262 , E-ISSN: 1463-9270

Output data

Year: 2006, Volume: 8, Number: 10, Pages: 883-886 Pages count : 4 DOI: 10.1039/b606120f

Tags

HYPERVALENT IODINE REAGENTS; SELECTIVE OXIDATION; AROMATIC-COMPOUNDS; ORGANIC-SYNTHESIS; MOLECULAR-SIEVES; HYDROGEN-PEROXIDE; 2-METHYLNAPHTHALENE; VITAMIN-K-3; ALLYLATION; CHEMISTRY

Authors

Zalomaeva Olga V. ^1,2 , Kholdeeva Oxana A. ¹ , Sorokin Alexander B. ²

Affiliations

1	Boreskov Institute of Catalysis, Novosibirsk, 630090, Pr. Ac. Lavrentieva 5, Russian Federation
2	Institut de Recherches sur la Catalyse, CNRS, Villeurbanne Cedex, 69626, 2 avenue A. Einstein, France

Funding (1)

Russian Foundation for Basic Research

05-03-34760

The oxidation of 2-allylphenol and different phenols bearing alcohol functional groups with aqueous H2O2 as oxidant and heterogeneous titanium-silicate Ti-MMM-2 as catalyst exhibits an unusual selectivity affording the corresponding p-quinones with good to moderate yield and keeping the other oxidizable sites intact. The use of hydrogen peroxide and heterogeneous titanium-silicate catalyst is a green alternative to the stoichiometric oxidation with hypervalent iodine compounds that provides better yields of structurally complex quinones in one step.

Zalomaeva O.V. , Kholdeeva O.A. , Sorokin A.B.
H2O2-Based Oxidation of Functionalized Phenols Containing Several Oxidizable Sites to p-Quinones Using a Mesoporous Titanium-Slicate Catalyst
Green Chemistry. 2006. V.8. N10. P.883-886. DOI: 10.1039/b606120f WOS Scopus РИНЦ ANCAN OpenAlex

Submitted:	May 2, 2006
Accepted:	Jun 28, 2006
Published online:	Jul 17, 2006

Web of science:	WOS:000241036200012
Scopus:	2-s2.0-33749518299
Elibrary:	13505048
Chemical Abstracts:	2006:1041945
Chemical Abstracts (print):	147:120099
OpenAlex:	W2133749841

DB	Citing
Web of science	19
Scopus	21
Elibrary	20
OpenAlex	21