Change of CO2 Carrying Capacity of CaO in Isothermal Recarbonation-Decomposition Cycles Full article
| Journal |
Industrial and Engineering Chemistry Research
ISSN: 0888-5885 , E-ISSN: 1520-5045 |
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| Output data | Year: 2007, Volume: 46, Number: 13, Pages: 4633-4638 Pages count : 6 DOI: 10.1021/ie0702328 | ||
| Tags | Calcium compounds; Carbonation; Decomposition; Sorbents; Thermogravimetric analysis | ||
| Authors |
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| Affiliations |
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Funding (3)
| 1 | Russian Foundation for Basic Research | 06-08-00258 |
| 2 | Russian Foundation for Basic Research | 06-08-08089 |
| 3 | Global Energy Association | MG-2006/04/5 |
Abstract:
The change of CO2 carrying capacity of CaO sorbents prepared from different precursors has been studied using thermogravimetric analysis in a long series of isothermal recarbonation−decomposition cycles in the temperature range of 750−850 °C. The residual capacity of the CaO sorbents after a large number of cycles was found to depend on the precursor type, the experimental temperature, and the duration of the recarbonation stage. The residual capacities of the CaO derived from the powdered calcium carbonates were much higher than that of the CaO produced from the crystalline CaCO3. A simple tentative model has been suggested, according to which recarbonation−decomposition cycles result in formation of the interconnected CaO network that acts as a refractory support and determines sorption properties of the material. By using a new model, a simple synthesis procedure has been suggested that produces CaO sorbents with high residual CO2 carrying capacities.
Cite:
Lysikov A.I.
, Salanov A.N.
, Okunev A.G.
Change of CO2 Carrying Capacity of CaO in Isothermal Recarbonation-Decomposition Cycles
Industrial and Engineering Chemistry Research. 2007. V.46. N13. P.4633-4638. DOI: 10.1021/ie0702328 WOS Scopus РИНЦ ANCAN OpenAlex
Change of CO2 Carrying Capacity of CaO in Isothermal Recarbonation-Decomposition Cycles
Industrial and Engineering Chemistry Research. 2007. V.46. N13. P.4633-4638. DOI: 10.1021/ie0702328 WOS Scopus РИНЦ ANCAN OpenAlex
Dates:
| Submitted: | Feb 10, 2007 |
| Accepted: | Apr 9, 2007 |
| Published online: | May 15, 2007 |
| Published print: | Jun 1, 2007 |
Identifiers:
| Web of science: | WOS:000247186900035 |
| Scopus: | 2-s2.0-34547306714 |
| Elibrary: | 13549110 |
| Chemical Abstracts: | 2007:521282 |
| Chemical Abstracts (print): | 147:145712 |
| OpenAlex: | W2141510090 |