Potentials of Gas Chromatography in the Determination of Reaction Products in the Catalytic Oxidation of Ammonia to Nitrogen(II) Oxide Full article
| Conference |
Annual Session of the Scientific Council on Analytical Chemistry of the Russian Academy of Sciences 12-17 Nov 2006 , Москва |
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| Journal |
Journal of Analytical Chemistry
ISSN: 1061-9348 , E-ISSN: 1608-3199 |
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| Output data | Year: 2007, Volume: 62, Number: 12, Pages: 1170-1175 Pages count : 6 DOI: 10.1134/S1061934807120131 | ||
| Tags | Nitrogen Oxide; Catalytic Oxidation; Ammonia Oxidation; Polymer Adsorbent; Sampling Valve | ||
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Abstract:
Peculiarities of the determination of nitrogen oxides and ammonia in the reaction products of ammonia oxidation are studied by gas chromatography. Particular attention was paid to the sampling problem. It is shown that in the course of the transportation of samples containing nitrogen(II) oxide and oxygen, the oxidation of nitrogen(II) oxide to nitrogen(IV) oxide takes place in the vapor phase. The conditions were found for suppressing or even eliminating the gas-phase reaction of NO oxidation to NO2. A procedure for the gas-chromatographic analysis of the reaction products in the catalytic oxidation of ammonia is proposed using several samples and packed columns, including the determination of NO with respect to NO2 formed in the gas-phase oxidation of NO.
Cite:
Zheivot V.I.
, Nikoro T.A.
, Krivoruchko V.N.
, Panina L.I.
, Pinaeva L.G.
, Isupova L.A.
Potentials of Gas Chromatography in the Determination of Reaction Products in the Catalytic Oxidation of Ammonia to Nitrogen(II) Oxide
Journal of Analytical Chemistry. 2007. V.62. N12. P.1170-1175. DOI: 10.1134/S1061934807120131 WOS Scopus РИНЦ ANCAN OpenAlex
Potentials of Gas Chromatography in the Determination of Reaction Products in the Catalytic Oxidation of Ammonia to Nitrogen(II) Oxide
Journal of Analytical Chemistry. 2007. V.62. N12. P.1170-1175. DOI: 10.1134/S1061934807120131 WOS Scopus РИНЦ ANCAN OpenAlex
Original:
Жейвот В.И.
, Никоро Т.А.
, Криворучко В.Н.
, Панина Л.И.
, Пинаева Л.Г.
, Исупова Л.А.
Изучение возможности определения методом газовой хроматографии продуктов реакции каталитического окисления аммиака в оксид азота(II)
Журнал аналитической химии. 2007. Т.62. №12. С.1297-1303. РИНЦ
Изучение возможности определения методом газовой хроматографии продуктов реакции каталитического окисления аммиака в оксид азота(II)
Журнал аналитической химии. 2007. Т.62. №12. С.1297-1303. РИНЦ
Dates:
| Submitted: | May 15, 2006 |
| Accepted: | Aug 21, 2006 |
| Published print: | Dec 1, 2007 |
Identifiers:
| Web of science: | WOS:000251189700013 |
| Scopus: | 2-s2.0-36348972379 |
| Elibrary: | 13563026 |
| Chemical Abstracts: | 2007:1368468 |
| Chemical Abstracts (print): | 148:321190 |
| OpenAlex: | W1973686565 |