Supported Titanium–Magnesium Catalysts with Different Titanium Content: Kinetic Peculiarities at Ethylene Homopolymerization and Copolymerization and Molecular Weight Characteristics of Polyethylene Full article
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Journal of Applied Polymer Science
ISSN: 0021-8995 , E-ISSN: 1097-4628 |
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| Output data | Year: 2006, Volume: 102, Number: 6, Pages: 5436-5442 Pages count : 7 DOI: 10.1002/app.25060 | ||
| Tags | Ethylene polymerization, Gel permeation chromatography (GPC), Molecular weight distribution (MWD), Polyethylene (PE), Size exclusion chromatography (SEC), Titanium-magnesium catalyst | ||
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Abstract:
The effect of Ti content on the activity of titanium–magnesium catalysts (TMC) and molecular weight distribution (MWD) of polyethylene (PE) produced has been studied. It was found that the activity enhances sharply as Ti content decreases from 0.6 to 0.07 wt %, and shows no significant changes in the Ti content range of 0.6–5.0 wt %. The maximum activity (36 kg PE/mmol Ti × h × bar C2H4) was observed for TMC with the lowest Ti content. The catalyst with low titanium content (∼ 0.1 wt % of Ti) produced PE with narrower MWD (Mw/Mn = 3.1–3.5) as compared to catalysts with higher titanium content (3–5 wt % of Ti; Mw/Mn = 4.8–5.0). New data on the effect of hydrogen on MWD of PE have been found. Increasing hydrogen concentration results in broadening the MWD of PE, especially in the case of TMC with high titanium content. The data presented indicate the heterogeneity of active centers of TMC in the reaction of chain transfer with hydrogen. The data on the ethylene–hexene-1 copolymerization over TMC with different titanium content are presented. Comonomer reactivity ratios were shown to be independent of the Ti content in TMC. Presumably the difference in activity of these catalysts is mainly caused by the difference in the number of active centers.
Cite:
Echevskaya L.G.
, Matsko M.A.
, Mikenas T.B.
, Nikitin V.E.
, Zakharov V.A.
Supported Titanium–Magnesium Catalysts with Different Titanium Content: Kinetic Peculiarities at Ethylene Homopolymerization and Copolymerization and Molecular Weight Characteristics of Polyethylene
Journal of Applied Polymer Science. 2006. V.102. N6. P.5436-5442. DOI: 10.1002/app.25060 WOS Scopus РИНЦ OpenAlex ANCAN
Supported Titanium–Magnesium Catalysts with Different Titanium Content: Kinetic Peculiarities at Ethylene Homopolymerization and Copolymerization and Molecular Weight Characteristics of Polyethylene
Journal of Applied Polymer Science. 2006. V.102. N6. P.5436-5442. DOI: 10.1002/app.25060 WOS Scopus РИНЦ OpenAlex ANCAN
Dates:
| Submitted: | Nov 14, 2005 |
| Accepted: | Jun 23, 2006 |
| Published online: | Sep 28, 2006 |
| Published print: | Dec 15, 2006 |
Identifiers:
| ≡ Web of science: | WOS:000241593800045 |
| ≡ Scopus: | 2-s2.0-33751320131 |
| ≡ Elibrary: | 13533280 |
| ≡ OpenAlex: | W2052428926 |
| ≡ Chemical Abstracts: | 2006:1188761 |
| ≡ Chemical Abstracts (print): | 146:82246 |