Model Pd-Based Bimetallic Supported Catalysts for Nitrate Electroreduction Full article
| Journal |
Journal of Molecular Catalysis A: Chemical
ISSN: 1381-1169 |
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| Output data | Year: 2007, Volume: 265, Number: 1-2, Pages: 141-147 Pages count : 7 DOI: 10.1016/j.molcata.2006.10.007 | ||||
| Tags | Bimetallic catalysis, Cu upd, Electroreduction, Nanoparticles, Nitrate reduction, Palladium | ||||
| Authors |
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| Affiliations |
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Funding (2)
| 1 | Council for Grants of the President of the Russian Federation | НШ-6526.2006.3 |
| 2 | North Atlantic Treaty Organization | NATO RIG.981941 |
Abstract:
An approach for in situ preparation of bimetallic Pd–Cu catalysts active in nitrate electroreduction is described. The catalysts are prepared by modification of the surface of Pd carbon-supported nanoparticles by monolayer of Cu. The morphology of Pd/C nanoparticles is characterized by HR-TEM and by their electrochemical properties in the adsorption of hydrogen and Cu adatoms. Modification of Pd surface by Cu adlayer results in significant increase of the activity in nitrate electroreduction. Dependencies of the reaction rate for Cu/Pd/C catalysts on the electrode potential, nitrate concentration and anion of supporting electrolyte are discussed.
Cite:
Pronkin S.N.
, Simonov P.A.
, Zaikovskii V.I.
, Savinova E.R.
Model Pd-Based Bimetallic Supported Catalysts for Nitrate Electroreduction
Journal of Molecular Catalysis A: Chemical. 2007. V.265. N1-2. P.141-147. DOI: 10.1016/j.molcata.2006.10.007 WOS Scopus РИНЦ OpenAlex ANCAN
Model Pd-Based Bimetallic Supported Catalysts for Nitrate Electroreduction
Journal of Molecular Catalysis A: Chemical. 2007. V.265. N1-2. P.141-147. DOI: 10.1016/j.molcata.2006.10.007 WOS Scopus РИНЦ OpenAlex ANCAN
Dates:
| Submitted: | Jul 19, 2006 |
| Accepted: | Oct 5, 2006 |
| Published online: | Oct 12, 2006 |
| Published print: | Mar 16, 2007 |
Identifiers:
| ≡ Web of science: | WOS:000245350600017 |
| ≡ Scopus: | 2-s2.0-33847652803 |
| ≡ Elibrary: | 13559945 |
| ≡ OpenAlex: | W2013086867 |
| ≡ Chemical Abstracts: | 2007:267983 |
| ≡ Chemical Abstracts (print): | 147:414938 |