Sciact
  • EN
  • RU

Variational Principles in Irreversible Thermodynamics with Application to Combustion Waves Full article

Journal Journal of Non-Equilibrium Thermodynamics
ISSN: 0340-0204 , E-ISSN: 1437-4358
Output data Year: 2011, Volume: 36, Pages: 55-73 Pages count : 19 DOI: 10.1515/JNETDY.2011.005
Tags Combustion wave, Entropy production minimization, Laminar combustion, Traveling waves
Authors Gerasev Alexander P. 1
Affiliations
1 Boreskov Institute of Catalysis, Siberian Division, Russian Academy of Sciences, prosp. Acad. Lavrent’eva, 5, Novosibirsk 630090, Russia.

Abstract: The thermodynamics of physicochemical processes in a reacting distributed kinetic system are considered, and the entropy balance equation for traveling waves of laminar combustion is derived for arbitrary Lewis number. Qualitative and numerical analysis of a dynamic system with a threedimensional phase space and of the local and complete entropy production in the system were performed. It is shown that the complete entropy production in the system is a functional of the traveling wave solution of the problem, possessing extreme properties, whose minimum corresponds to the only physically meaningful traveling wave solution. The procedure of “cut-off” (zeroing) of the reaction rate is justified by methods of nonequilibrium thermodynamics. A variational formulation of the problem is presented for calculation of a steady laminar combustion wave.
Cite: Gerasev A.P.
Variational Principles in Irreversible Thermodynamics with Application to Combustion Waves
Journal of Non-Equilibrium Thermodynamics. 2011. V.36. P.55-73. DOI: 10.1515/JNETDY.2011.005 WOS Scopus РИНЦ OpenAlex
Dates:
Submitted: Feb 4, 2010
Accepted: Apr 19, 2010
Published print: May 1, 2011
Published online: Jul 7, 2011
Identifiers:
Web of science: WOS:000292643400004
Scopus: 2-s2.0-79960219792
Elibrary: 16994022
OpenAlex: W2315322278
Citing:
DB Citing
Web of science 6
Scopus 6
Elibrary 7
OpenAlex 6
Altmetrics: