Dynamics of Water Vapor Sorption in a CaCl2/Silica Gel/Binder Bed: The Effect of the Bed Pore Structure Full article
| Journal |
Kinetics and Catalysis
ISSN: 0023-1584 , E-ISSN: 1608-3210 |
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| Output data | Year: 2006, Volume: 47, Number: 5, Pages: 776-781 Pages count : 6 DOI: 10.1134/S0023158406050181 | ||||
| Tags | Heat Pump; Water Sorption; Binder Content; Sorbed Water; Water Vapor Sorption | ||||
| Authors |
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| Affiliations |
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Funding (5)
| 1 | Russian Foundation for Basic Research | 04-02-81028 |
| 2 | Russian Foundation for Basic Research | 05-02-16953 |
| 3 | Russian Foundation for Basic Research | 05-03-34762 |
| 4 | Global Energy Association | MG-2005/04/3 |
| 5 | International Association for the Promotion of Co-operation with Scientists from the New Independent States of the Former Soviet Union | 2003-51-6260 |
Abstract:
The dynamics of water vapor sorption in a compact, binder-containing bed of a CaCl2-in-silica-gelpores sorbent has been investigated by NMR microscopy. The procedure suggested for the preparation of this bed allows the porous structure of the bed to be modified in a wide range. The bed pore structure and water transfer in the bed have been studied in relation to the particle size of the initial silica gel, the size of mesopores in the sorbent particles, and the binder content. By varying these parameters, it is possible to optimize the ratio of the diffusion resistance of the interparticle macropores to that of the internal mesopores of the particles. If sorption is controlled by water diffusion in the macropores, a sorption front forms in the sample to move inside the bed. The distance traveled by the front is proportional to the sorption time to the power 1/2. The effective diffusion coefficient of water in the macropores is estimated from the front motion dynamics to be between 0.8 × 10−9 and 3.0 × 10−9 m2/s, depending on the porous structure of the bed.
Cite:
Aristov Y.I.
, Koptyug I.V.
, Gordeeva L.G.
, Ilina L.Y.
, Glaznev I.S.
Dynamics of Water Vapor Sorption in a CaCl2/Silica Gel/Binder Bed: The Effect of the Bed Pore Structure
Kinetics and Catalysis. 2006. V.47. N5. P.776-781. DOI: 10.1134/S0023158406050181 WOS Scopus РИНЦ ANCAN OpenAlex
Dynamics of Water Vapor Sorption in a CaCl2/Silica Gel/Binder Bed: The Effect of the Bed Pore Structure
Kinetics and Catalysis. 2006. V.47. N5. P.776-781. DOI: 10.1134/S0023158406050181 WOS Scopus РИНЦ ANCAN OpenAlex
Original:
Аристов Ю.И.
, Коптюг И.В.
, Гордеева Л.Г.
, Ильина Л.Ю.
, Глазнев И.С.
Динамика сорбции паров воды в слое СаСl2/силикагель/связующее: влияние пористой структуры слоя
Кинетика и катализ. 2006. Т.47. №5. С.799-804. RSCI РИНЦ
Динамика сорбции паров воды в слое СаСl2/силикагель/связующее: влияние пористой структуры слоя
Кинетика и катализ. 2006. Т.47. №5. С.799-804. RSCI РИНЦ
Dates:
| Submitted: | Feb 10, 2005 |
| Published print: | Sep 1, 2006 |
Identifiers:
| Web of science: | WOS:000241045200018 |
| Scopus: | 2-s2.0-33749423078 |
| Elibrary: | 13530544 |
| Chemical Abstracts: | 2006:1026911 |
| Chemical Abstracts (print): | 145:461070 |
| OpenAlex: | W2093861376 |