Liquid-Phase Oxidation of Benzothiophene and Dibenzothiophene by Cumyl Hydroperoxide in the Presence of Catalysts Based on Supported Metal Oxides Научная публикация
| Журнал |
Kinetics and Catalysis
ISSN: 0023-1584 , E-ISSN: 1608-3210 |
||||
|---|---|---|---|---|---|
| Вых. Данные | Год: 2008, Том: 49, Номер: 5, Страницы: 644-652 Страниц : 9 DOI: 10.1134/S002315840805008X | ||||
| Ключевые слова | Dibenzothiophene; Benzothiophene; Oxidative Desulfurization; Cumyl; Support Metal Oxide | ||||
| Авторы |
|
||||
| Организации |
|
Реферат:
The liquid-phase oxidation of benzothiophene and dibenzothiophene by cumyl hydroperoxide in the presence of supported metal oxide catalysts was carried out in octane in an N2 atmosphere at 50–80°C. The cumyl hydroperoxide, benzothiophene, and dibenzothiophene conversions and the yield of sulfones were determined for catalysts of various natures. In the presence of MoO3/SiO2, the most efficient and most readily regenerable catalyst, the benzothiophene conversion was ∼60% and the dibenzothiophene conversion was as high as 100% upon almost complete consumption of cumyl hydroperoxide. The influence of unsaturated and aromatic compounds (oct-1-ene, toluene) on the catalytic effect was studied. The kinetics of substrate oxidation and cumyl hydroperoxide decomposition and an analysis of the cumyl hydroperoxide conversion products suggested a benzothiophene and dibenzothiophene oxidation mechanism including the formation of an intermediate complex of the hydroperoxide with the catalyst and the substrate and its transformation via heterolytic and homolytic routes.
Библиографическая ссылка:
Kuznetsova L.I.
, Detusheva L.G.
, Kuznetsova N.I.
, Duplyakin V.K.
, Likholobov V.A.
Liquid-Phase Oxidation of Benzothiophene and Dibenzothiophene by Cumyl Hydroperoxide in the Presence of Catalysts Based on Supported Metal Oxides
Kinetics and Catalysis. 2008. V.49. N5. P.644-652. DOI: 10.1134/S002315840805008X WOS Scopus РИНЦ CAPlusCA OpenAlex
Liquid-Phase Oxidation of Benzothiophene and Dibenzothiophene by Cumyl Hydroperoxide in the Presence of Catalysts Based on Supported Metal Oxides
Kinetics and Catalysis. 2008. V.49. N5. P.644-652. DOI: 10.1134/S002315840805008X WOS Scopus РИНЦ CAPlusCA OpenAlex
Оригинальная:
Кузнецова Л.И.
, Детушева Л.Г.
, Кузнецова Н.И.
, Дуплякин В.К.
, Лихолобов В.А.
Жидкофазное окисление бензотиофена и дибензотиофена гидроперекисью кумила в присутствии катализаторов на основе нанесенных оксидов металлов
Кинетика и катализ. 2008. Т.49. №5. С.675-683. РИНЦ
Жидкофазное окисление бензотиофена и дибензотиофена гидроперекисью кумила в присутствии катализаторов на основе нанесенных оксидов металлов
Кинетика и катализ. 2008. Т.49. №5. С.675-683. РИНЦ
Даты:
| Поступила в редакцию: | 28 мая 2007 г. |
| Опубликована в печати: | 1 сент. 2008 г. |
| Опубликована online: | 30 сент. 2008 г. |
Идентификаторы БД:
| Web of science: | WOS:000259698000008 |
| Scopus: | 2-s2.0-53249097856 |
| РИНЦ: | 13597103 |
| Chemical Abstracts: | 2008:1175927 |
| Chemical Abstracts (print): | 151:317550 |
| OpenAlex: | W1973813627 |