Ethylene Polymerization over Supported Titanium-Magnesium Catalysts: Heterogeneity of Active Centers and Effect of Catalyst Composition on the Molecular Mass Distribution of Polymer Full article
| Conference |
5th International Workshop on Heterogeneous Ziegler‐Natta Catalysts 18-21 Mar 2007 , Ishikawa |
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| Journal |
Macromolecular Symposia
ISSN: 1022-1360 , E-ISSN: 1521-3900 |
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| Output data | Year: 2007, Volume: 260, Number: Heterogeneous Ziegler-Natta Catalysts, Pages: 184-188 Pages count : 5 DOI: 10.1002/masy.200751427 | ||
| Tags | Fractionation of polymers, Molecular weight distribution/molar mass distribution, Polyethylene (PE), Titanium-magnesium catalysts (TMC), Ziegler-natta polymerization | ||
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Abstract:
New experimental approach was used for analysis of molecular weight distribution (MWD) of polymers produced over titanium-magnesium catalysts (TMC). Polymers were fractionated on to fractions with narrow MWD (polydispersity (PD) values Mw/Mn ≤ 2). Then some of these fractions were combined to get the minimal quantity of fractions with PD values close to 2 (Flory components). It was found that three fractions corresponding to three groups of active centers are sufficient for proper fitting experimental MWD curve for PE obtained over TMC with different Ti content and with different hydrogen concentration in polymerization.
Cite:
Zakharov V.
, Matsko M.
, Echevskaya L.
, Mikenas T.
Ethylene Polymerization over Supported Titanium-Magnesium Catalysts: Heterogeneity of Active Centers and Effect of Catalyst Composition on the Molecular Mass Distribution of Polymer
Macromolecular Symposia. 2007. V.260. NHeterogeneous Ziegler-Natta Catalysts. P.184-188. DOI: 10.1002/masy.200751427 WOS Scopus РИНЦ OpenAlex ANCAN
Ethylene Polymerization over Supported Titanium-Magnesium Catalysts: Heterogeneity of Active Centers and Effect of Catalyst Composition on the Molecular Mass Distribution of Polymer
Macromolecular Symposia. 2007. V.260. NHeterogeneous Ziegler-Natta Catalysts. P.184-188. DOI: 10.1002/masy.200751427 WOS Scopus РИНЦ OpenAlex ANCAN
Dates:
| Published print: | Dec 1, 2007 |
| Published online: | Jan 7, 2008 |
Identifiers:
| ≡ Web of science: | WOS:000252873800027 |
| ≡ Scopus: | 2-s2.0-38849124260 |
| ≡ Elibrary: | 13540812 |
| ≡ OpenAlex: | W2117386574 |
| ≡ Chemical Abstracts: | 2008:193315 |
| ≡ Chemical Abstracts (print): | 148:380004 |