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Composites "Lithium Halides in Silica Gel Pores": Methanol Sorption Equilibrium Full article

Journal Microporous and Mesoporous Materials
ISSN: 1387-1811 , E-ISSN: 1873-3093
Output data Year: 2008, Volume: 112, Number: 1-3, Pages: 254-261 Pages count : 8 DOI: 10.1016/j.micromeso.2007.09.040
Tags Adsorption, Composite materials, Lithium halides, Methanol, Silica gel
Authors Gordeeva Larisa G. 1 , Freni Angelo 2 , Krieger Tamara A. 1 , Restuccia Giovanni 2 , Aristov Yuri I. 1
Affiliations
1 Boreskov Institute of Catalysis, Pr. Ak. Lavrentieva 5, 630090 Novosibirsk, Russia
2 Istituto di Tecnologie Avanzate per l’Energia ‘‘Nicola Giordano’’, S. Lucia Sopra Contesse 5, 98126 Messina, Italy

Funding (3)

1 Russian Foundation for Basic Research 05-02-16953
2 Russian Foundation for Basic Research 05-08-50223
3 National Research Council 0030491 (11.04.2006)

Abstract: This paper presents the methanol sorption equilibrium and phase composition of two composite sorbents ‘‘LiCl and LiBr confined to mesopores of silica gel’’. Chemical phase analysis of the samples was performed by the differential dissolution method. Phase transformation of the composites during methanol sorption was characterized in situ by X-ray diffraction analysis. The isobars of methanol sorption on the composites were measured in the temperature range T = 293–423 K and for methanol pressure PMeOH = 21–300 mbar using a thermo-gravimetric technique. It was found that the two composites showed an outstanding sorption capacity wmax = 0.8 g/g and an energy storage ability Emax = 1.0 kJ/g, which could be attractive for development of efficient adsorptive cooling/heating and energy storage systems driven by a low temperature heat source
Cite: Gordeeva L.G. , Freni A. , Krieger T.A. , Restuccia G. , Aristov Y.I.
Composites "Lithium Halides in Silica Gel Pores": Methanol Sorption Equilibrium
Microporous and Mesoporous Materials. 2008. V.112. N1-3. P.254-261. DOI: 10.1016/j.micromeso.2007.09.040 WOS Scopus РИНЦ ANCAN OpenAlex
Dates:
Submitted: Jun 29, 2007
Accepted: Sep 27, 2007
Published online: Oct 1, 2007
Published print: Jul 1, 2008
Identifiers:
Web of science: WOS:000256713300029
Scopus: 2-s2.0-43249128090
Elibrary: 13590974
Chemical Abstracts: 2008:606304
Chemical Abstracts (print): 151:87255
OpenAlex: W2033801737
Citing:
DB Citing
Web of science 54
Scopus 57
Elibrary 53
OpenAlex 61
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