Sciact
  • EN
  • RU

Study of Palladium Catalyst Deactivation in Synthesis of 4,10-Diformyl-2,6,8,12-tetraacetyl-2,4,6,8,10,12-hexaazaisowurtzitane Full article

Journal Reaction Kinetics and Catalysis Letters
ISSN: 0133-1736 , E-ISSN: 1588-2837
Output data Year: 2007, Volume: 92, Number: 2, Pages: 293-302 Pages count : 10 DOI: 10.1007/s11144-007-5203-4
Tags CL-20 synthesis, Debenzylation, Palladium-based catalyst, Pd/C deactivation
Authors Koskin Anton P. 1 , Simakova Irina L. 1 , Parmon Valentin N. 1
Affiliations
1 Boreskov Institute of Catalysis

Abstract: Polycyclic nitramine hexanitrohexaazaisowurtzitane (HNIW, CL-20) is synthesized via hydrodebenzylation of a precursor over palladium-based catalyst. In the present work, we studied the influence of the synthesis method of the palladium-based catalyst on the catalyst behavior during the hydrodebenzylation reaction of 2,4,6,8,10,12-hexabenzyl-2,4,6,8,10,12-hexaazatetracyclo[5.5.0.03,11.05,9] dodecane.
Cite: Koskin A.P. , Simakova I.L. , Parmon V.N.
Study of Palladium Catalyst Deactivation in Synthesis of 4,10-Diformyl-2,6,8,12-tetraacetyl-2,4,6,8,10,12-hexaazaisowurtzitane
Reaction Kinetics and Catalysis Letters. 2007. V.92. N2. P.293-302. DOI: 10.1007/s11144-007-5203-4 WOS Scopus РИНЦ ANCAN OpenAlex
Dates:
Submitted: Aug 30, 2007
Accepted: Sep 14, 2007
Published online: Nov 29, 2007
Published print: Dec 1, 2007
Identifiers:
Web of science: WOS:000251309400012
Scopus: 2-s2.0-36649032449
Elibrary: 13563075
Chemical Abstracts: 2007:1368546
Chemical Abstracts (print): 149:471442
OpenAlex: W2043374868
Citing:
DB Citing
Web of science 18
Scopus 19
Elibrary 18
OpenAlex 18
Altmetrics: