Preparation of Pd/C Catalysts via Deposition of Palladium Hydroxide onto Sibunit Carbon and Their Application to Partial Hydrogenation of Rapeseed Oil Научная публикация
| Журнал |
Reaction Kinetics and Catalysis Letters
ISSN: 0133-1736 , E-ISSN: 1588-2837 |
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| Вых. Данные | Год: 2008, Том: 95, Номер: 1, Страницы: 3-12 Страниц : 10 DOI: 10.1007/s11144-008-5373-8 | ||
| Ключевые слова | Cis-trans isomerization, Pd/C catalysts, Vegetable oil hydrogenation | ||
| Авторы |
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| Организации |
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Реферат:
Pd/Sibunit catalysts were prepared by deposition of palladium hydroxide onto the support surface in an alkaline medium. It was found that the palladium distribution throughout the catalyst grain, and the dispersion of Pd particles depend on (i) the order of the addition of H2PdCl4 and Na2CO3 to carbon suspension, (ii) Na2CO3 to H2PdCl4 ratio, and (iii) aging time of the mixture H2PdCl4 + Na2CO3 before its addition to the carbon. The catalysts were tested in the hydrogenation of cyclohexene and rapeseed oil under static conditions. The yield of trans-isomers as products of partial hydrogenation of rapeseed oil was found to decrease with decreasing the Pd particle size in the catalysts, as well as with increasing the Pd concentration on the periphery of the support grains.
Библиографическая ссылка:
Simakova O.A.
, Simonov P.A.
, Romanenko A.V.
, Simakova I.L.
Preparation of Pd/C Catalysts via Deposition of Palladium Hydroxide onto Sibunit Carbon and Their Application to Partial Hydrogenation of Rapeseed Oil
Reaction Kinetics and Catalysis Letters. 2008. V.95. N1. P.3-12. DOI: 10.1007/s11144-008-5373-8 WOS Scopus РИНЦ CAPlusCA OpenAlex
Preparation of Pd/C Catalysts via Deposition of Palladium Hydroxide onto Sibunit Carbon and Their Application to Partial Hydrogenation of Rapeseed Oil
Reaction Kinetics and Catalysis Letters. 2008. V.95. N1. P.3-12. DOI: 10.1007/s11144-008-5373-8 WOS Scopus РИНЦ CAPlusCA OpenAlex
Даты:
| Поступила в редакцию: | 30 июн. 2008 г. |
| Принята к публикации: | 9 июл. 2008 г. |
| Опубликована в печати: | 1 окт. 2008 г. |
| Опубликована online: | 17 дек. 2008 г. |
Идентификаторы БД:
| Web of science: | WOS:000260113900001 |
| Scopus: | 2-s2.0-57649227422 |
| РИНЦ: | 13588200 |
| Chemical Abstracts: | 2008:1314101 |
| Chemical Abstracts (print): | 151:126261 |
| OpenAlex: | W1998753952 |