The Kinetics of Thermal Isomerization of β-pinene and a Mixture of β- and α-pinenes in Supercritical Ethanol Full article
| Journal |
The Journal of Supercritical Fluids
ISSN: 0896-8446 , E-ISSN: 1872-8162 |
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| Output data | Year: 2008, Volume: 45, Number: 1, Pages: 74-79 Pages count : 6 DOI: 10.1016/j.supflu.2007.12.005 | ||||||
| Tags | α- and β-pinenes, Kinetic, Monoterpenes, Supercritical ethanol, Thermal isomerization | ||||||
| Authors |
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Abstract:
Thermal isomerization of -pinene and equimolar mixture of - and -pinenes in supercritical ethanol was studied experimentally. The reactivity of structurally similar - and -pinenes were compared in the same supercritical solvent. It was shown that both pinenes undergo thermal transformations independently of one another upon co-thermolysis in supercritical (SC) ethanol. Conversion of -pinene yields monocyclic limonene as the main product, and -pinene gives acyclic -myrcene. This study allowed developing the first kinetic model of -pinene thermolysis in SC ethanol.
Cite:
Ermakova A.I.
, Chibiryaev A.M.
, Kozhevnikov I.V.
, Anikeev V.I.
The Kinetics of Thermal Isomerization of β-pinene and a Mixture of β- and α-pinenes in Supercritical Ethanol
The Journal of Supercritical Fluids. 2008. V.45. N1. P.74-79. DOI: 10.1016/j.supflu.2007.12.005 WOS Scopus РИНЦ ANCAN OpenAlex
The Kinetics of Thermal Isomerization of β-pinene and a Mixture of β- and α-pinenes in Supercritical Ethanol
The Journal of Supercritical Fluids. 2008. V.45. N1. P.74-79. DOI: 10.1016/j.supflu.2007.12.005 WOS Scopus РИНЦ ANCAN OpenAlex
Dates:
| Submitted: | Sep 15, 2007 |
| Accepted: | Dec 7, 2007 |
| Published online: | Dec 27, 2007 |
| Published print: | May 1, 2008 |
Identifiers:
| Web of science: | WOS:000255297400010 |
| Scopus: | 2-s2.0-40949165063 |
| Elibrary: | 13585024 |
| Chemical Abstracts: | 2008:383553 |
| Chemical Abstracts (print): | 150:144665 |
| OpenAlex: | W2025079160 |