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Phenol Oxidation in Supercritical Water in a Well-Stirred Continuous Reactor Научная публикация

Журнал Theoretical Foundations of Chemical Engineering
ISSN: 0040-5795 , E-ISSN: 1608-3431
Вых. Данные Год: 2006, Том: 40, Номер: 2, Страницы: 168-174 Страниц : 7 DOI: 10.1134/S0040579506020096
Ключевые слова Phenol; Enthalpy; Heat Capacity; Thermodynamic Property; Total Pressure
Авторы Yermakova A. 1 , Mikenin P.E. 1 , Anikeev V.I. 1
Организации
1 Boreskov Institute of Catalysis, Siberian Division, Russian Academy of Sciences, pr. akademika Lavrent’eva 5, Novosibirsk, 630090, Russia

Реферат: A well-stirred reactor for phenol and acetic acid oxidation in supercritical water is considered. A mathematical model of an adiabatic reactor is formulated. A numerical algorithm for solving the model equations using the homotopy method is developed. The model takes into account specific features of processes under supercritical conditions, namely, the changes in the thermodynamic properties (enthalpy, heat capacity, and critical parameters) of mixtures with a change in pressure and temperature. The thermodynamic properties are calculated by methods of nonideal thermodynamics. It is shown that there is a multiplicity of steady-state solutions at various reactor performances. The results of numerical analysis of the effect of the inlet flow temperature, the amount of methanol (fuel) fed, and the total pressure on the reactor performance are presented.
Библиографическая ссылка: Yermakova A. , Mikenin P.E. , Anikeev V.I.
Phenol Oxidation in Supercritical Water in a Well-Stirred Continuous Reactor
Theoretical Foundations of Chemical Engineering. 2006. V.40. N2. P.168-174. DOI: 10.1134/S0040579506020096 WOS Scopus РИНЦ CAPlusCA OpenAlex
Оригинальная: Ермакова А. , Микенин П.Е. , Аникеев В.И.
Окисление фенола в сверхкритической воде в проточном реакторе идеального смешения
Теоретические основы химической технологии. 2006. Т.40. №2. С.184-190. RSCI РИНЦ
Даты:
Поступила в редакцию: 25 апр. 2005 г.
Опубликована в печати: 1 мар. 2006 г.
Идентификаторы БД:
Web of science: WOS:000237235800009
Scopus: 2-s2.0-33646189175
РИНЦ: 13515109
Chemical Abstracts: 2006:373346
Chemical Abstracts (print): 146:186298
OpenAlex: W2063017290
Цитирование в БД:
БД Цитирований
Web of science 5
Scopus 8
РИНЦ 9
OpenAlex 6
Альметрики: