Sm-Doped Praseodymium Nickelates-Cobaltites and Their Nanocomposites with Y-Doped Ceria as Promising Cathode Materials | Sciact - CRIS-system of Boreskov Institute of Catalysis

Sm-Doped Praseodymium Nickelates-Cobaltites and Their Nanocomposites with Y-Doped Ceria as Promising Cathode Materials Full article

Journal

Integrated Ferroelectrics
ISSN: 1058-4587 , E-ISSN: 1607-8489

Output data

Year: 2016, Volume: 173, Pages: 71-81 Pages count : 11 DOI: 10.1080/10584587.2016.1184506

Tags

SOFC; cathodes; Sm-doped nickelates-cobaltites of Pr; Y-doped ceria; nanocomposites; synthesis; real structure; cations redistribution; oxygen isotope heteroexchange; oxygen self-diffusion coefficients

Authors

Sadykov V.A. ^1,2 , Eremeev N.F. ¹ , Amanbaeva D.G. ^1,3 , Krieger T.A. ¹ , Fedorova Yu.E. ^1,4 , Bobin A.S. ^1,2 , Pelipenko V.V. ¹ , Sadovskaya E.M. ^1,2 , Muzykantov V.S. ¹ , Ishchenko A.V. ^1,2

Affiliations

1	Boreskov Institute of Catalysis SB RAS, Novosibirsk, Russia
2	Novosibirsk State University, Novosibirsk, Russia
3	Novosibirsk State Technical University, Novosibirsk, Russia
4	Novosibirsk State Pedagogical University, Novosibirsk, Russia

Funding (3)

1	Federal Agency for Scientific Organizations	V.45.3.8.
2	European Commission	604296 FP7-NMP-2013-LARGE-7 BIOGO
3	The Ministry of Education and Science of the Russian Federation	Проект 5-100

This work aims at elucidating effects of composition and microstructure of materials based upon Pr1-ySmyNi1-xCoxO3-δ perovskites on their oxygen mobility. Pr1-ySmyNi1-xCoxO3-δ and their composites with Y-doped ceria are perspective materials for intermediate temperature solid oxide fuel cells and oxygen separation membranes. Doping PrNi1-xCoxO3-δ by Sm results in suppression of the fast channel of oxygen diffusion along extended defects due to Sm segregation in their vicinity. For nanocomposites moderate doping by Sm enhances fast oxygen diffusion in fluorite phase domains and along perovskite-fluorite interface due to a higher disordering caused by incorporation of both Pr and Sm cations into Y-doped ceria

Sadykov V.A. , Eremeev N.F. , Amanbaeva D.G. , Krieger T.A. , Fedorova Y.E. , Bobin A.S. , Pelipenko V.V. , Sadovskaya E.M. , Muzykantov V.S. , Ishchenko A.V.
Sm-Doped Praseodymium Nickelates-Cobaltites and Their Nanocomposites with Y-Doped Ceria as Promising Cathode Materials
Integrated Ferroelectrics. 2016. V.173. P.71-81. DOI: 10.1080/10584587.2016.1184506 WOS Scopus РИНЦ ANCAN OpenAlex

Submitted:	Oct 5, 2015
Published online:	Jun 17, 2016
Published print:	Jul 23, 2016
Accepted:	Dec 12, 2016

Web of science:	WOS:000381389900012
Scopus:	2-s2.0-84975063345
Elibrary:	27128739
Chemical Abstracts:	2016:1054081
Chemical Abstracts (print):	166:267141
OpenAlex:	W2425357682

DB	Citing
Web of science	1
Scopus	2
Elibrary	1
OpenAlex	1