Structure of Polynuclear Palladium(II) Hydroxocomplexes and the Mechanism of Their Adsorption by Carbon Materials Full article
| Journal |
Russian Chemical Bulletin
ISSN: 1066-5285 , E-ISSN: 1573-9171 |
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| Output data | Year: 1996, Volume: 45, Number: 6, Pages: 1296-1302 Pages count : 7 DOI: 10.1007/BF01434200 | ||
| Tags | Carbon material, adsorption, Molecule structure modeling, Palladium(II), hydrolysis, polynuclear hydroxocomplexes (PHC), Radial atomic distribution method, X-ray phase analysis, electron microscopy, Synthesis of microscopic images | ||
| Authors |
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| Affiliations |
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Funding (2)
| 1 | Russian Foundation for Basic Research | 93-03-04836 |
| 2 | International Science Foundation | RP5 300 |
Abstract:
Adsorption of polynuclear palladium(ii) hydroxocomplexes (PHC) by carbon materials (CM) was studied. It was found that PHC are adsorbed from aqueous solutions without a change in their chemical composition and are composed of clusters (<10 A) with metalmetal distances typical of the PdO chain structure. Three-dimensional ordered particles with the PdO structure were formed upon adsorption of PlIC on carbon materials at room temperature or after the PHC suspension was dried in air at 400 °C (the size of the particles was 15 and 25 A, respectively). Calculation of the electron-microscopic images of the adsorbed PHC with atomic resolution based on crystal structure modeling showed that PdO particles containing -100 palladium atoms is the final product after drying of the adsorbed PHC.
Cite:
Troitskii S.Y.
, Chuvilin A.L.
, Bogdanov S.V.
, Moroz E.M.
, Likholobov V.A.
Structure of Polynuclear Palladium(II) Hydroxocomplexes and the Mechanism of Their Adsorption by Carbon Materials
Russian Chemical Bulletin. 1996. V.45. N6. P.1296-1302. DOI: 10.1007/BF01434200 WOS Scopus РИНЦ OpenAlex
Structure of Polynuclear Palladium(II) Hydroxocomplexes and the Mechanism of Their Adsorption by Carbon Materials
Russian Chemical Bulletin. 1996. V.45. N6. P.1296-1302. DOI: 10.1007/BF01434200 WOS Scopus РИНЦ OpenAlex
Original:
Троицкий С.Ю.
, Чувилин А.Л.
, Богданов С.В.
, Мороз Э.М.
, Лихолобов В.А.
Структура полиядерных гидроксокомплексов палладия(II) и механизм их адсорбции углеродными материалами
Известия Академии наук. Серия химическая. 1996. №6. С.1366-1372. РИНЦ ANCAN
Структура полиядерных гидроксокомплексов палладия(II) и механизм их адсорбции углеродными материалами
Известия Академии наук. Серия химическая. 1996. №6. С.1366-1372. РИНЦ ANCAN
Dates:
| Submitted: | Jun 19, 1995 |
| Published print: | Jun 1, 1996 |
Identifiers:
| Web of science: | WOS:A1996VK10500006 |
| Scopus: | 2-s2.0-21444455896 |
| Elibrary: | 13239249 |
| OpenAlex: | W2086631457 |