Silica-Supported Silver-Containing OMS-2 Catalysts for Ethanol Oxidative Dehydrogenation Научная публикация
| Конференция |
11th European Workshop on Selective Oxidation - Selectivity in Oxidation - Key to New Resources Valorization (ISO) during the 12th European Congress on Catalysis - Balancing the Use of Fossil and Renewable Resources (Europacat) 30 авг. - 4 сент. 2015 , Kazan |
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| Журнал |
Catalysis Today
ISSN: 0920-5861 , E-ISSN: 1873-4308 |
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| Вых. Данные | Год: 2016, Том: 278, Страницы: 164-173 Страниц : 10 DOI: 10.1016/j.cattod.2016.05.058 | ||||
| Ключевые слова | Ethanol, Manganese dioxide, Octahedral molecular sieves, Selective oxidation, Silver | ||||
| Авторы |
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| Организации |
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Информация о финансировании (1)
| 1 | Национальный исследовательский Томский государственный университет | 8.2.07.2015 |
Реферат:
The silver-modified cryptomelane-type crystalline and silica-supported OMS-2 catalysts (Ag/OMS-2 and Ag/OMS-2/SiO2, respectively) were prepared by impregnation, co-precipitation, and consecutive impregnation methods and tested in selective oxidation of ethanol to acetaldehyde. Modifying OMS-2 and OMS-2/SiO2 catalysts by silver was shown to improve the redox properties of the catalysts and increase the ethanol oxidation rate. However, selectivity to acetaldehyde decreased with increased reaction temperature due to intensification of total oxidation on the Ag-MnOx sites. Preparation method of the catalyst affected the Ag localization and catalytic activity. Introducing silver into the OMS-2 channels provided a higher ethanol oxidation rate. The use of silica support for Ag/OMS-2 composites improved the selectivity towards acetaldehyde at higher temperatures and, therefore, increased the acetaldehyde yield in comparison with crystalline samples
Библиографическая ссылка:
Dutov V.V.
, Mamontov G.V.
, Sobolev V.I.
, Vodyankina O.V.
Silica-Supported Silver-Containing OMS-2 Catalysts for Ethanol Oxidative Dehydrogenation
Catalysis Today. 2016. V.278. P.164-173. DOI: 10.1016/j.cattod.2016.05.058 WOS Scopus РИНЦ CAPlusCA OpenAlex
Silica-Supported Silver-Containing OMS-2 Catalysts for Ethanol Oxidative Dehydrogenation
Catalysis Today. 2016. V.278. P.164-173. DOI: 10.1016/j.cattod.2016.05.058 WOS Scopus РИНЦ CAPlusCA OpenAlex
Даты:
| Поступила в редакцию: | 31 дек. 2015 г. |
| Принята к публикации: | 20 мая 2016 г. |
| Опубликована online: | 10 июл. 2016 г. |
| Опубликована в печати: | 1 дек. 2016 г. |
Идентификаторы БД:
| Web of science: | WOS:000388053000021 |
| Scopus: | 2-s2.0-84992747344 |
| РИНЦ: | 28170042 |
| Chemical Abstracts: | 2016:1148522 |
| Chemical Abstracts (print): | 165:500935 |
| OpenAlex: | W2469139819 |