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Microstructural Changes in La1−xCaxCoO3−δ Solid Solutions Under the Influence of Catalytic Reaction of Methane Combustion Научная публикация

Конференция EuropaCat-XII: 12th European Congress on Catalysis “Catalysis: Balancing the use of fossil and renewable resources”
30 авг. - 4 сент. 2015 , Казань
Журнал Topics in Catalysis
ISSN: 1022-5528 , E-ISSN: 1572-9028
Вых. Данные Год: 2016, Том: 59, Номер: 15-16, Страницы: 1354-1360 Страниц : 7 DOI: 10.1007/s11244-016-0661-4
Ключевые слова HRTEM, Oxidation, Perovskite, Planar defects, XRD
Авторы Gerasimov E. 1,2 , Kulikovskaya N. 1 , Chuvilin A. 3,4 , Isupova L. 1 , Tsybulya S. 1,2
Организации
1 Boreskov Institute of Catalysis, Novosibirsk, Russia 630090
2 Novosibirsk State University, Novosibirsk, Russia 630090
3 CIC nanoGUNE Consolider, 20018 San Sebastia´n, Spain
4 IKERBASQUE Basque Foundation for Science, 48013 Bilbao, Spain

Информация о финансировании (2)

1 Российский научный фонд 14-23-00037
2 European Commission 295180 FP7-PEOPLE-2011-IRSES

Реферат: Degradation of the surface of solid solutions La1−xCaxCoO3−δ (0.4 ≥ x ≥ 0) synthesized by the Pechini method was observed after catalytic oxidation of methane. According to XRD analysis, after the catalytic oxidation of CH4, the crystal structure of the samples did not change significantly, but HRTEM indicated the formation of nanoheterogeneities on the surface of the perovskite phase. Planar defects are formed in the direction of the crystallographic planes (111). Under the action of the reaction medium, areas with alternating layers having the perovskite and brownmillerite structure appeared in La0.6Ca0.4CoO3−δ.
Библиографическая ссылка: Gerasimov E. , Kulikovskaya N. , Chuvilin A. , Isupova L. , Tsybulya S.
Microstructural Changes in La1−xCaxCoO3−δ Solid Solutions Under the Influence of Catalytic Reaction of Methane Combustion
Topics in Catalysis. 2016. V.59. N15-16. P.1354-1360. DOI: 10.1007/s11244-016-0661-4 WOS Scopus РИНЦ CAPlusCA OpenAlex
Даты:
Опубликована online: 18 июл. 2016 г.
Опубликована в печати: 1 сент. 2016 г.
Идентификаторы БД:
Web of science: WOS:000382849100010
Scopus: 2-s2.0-84984920632
РИНЦ: 26872825
Chemical Abstracts: 2016:1194814
Chemical Abstracts (print): 165:304571
OpenAlex: W2505336844
Цитирование в БД:
БД Цитирований
Web of science 4
Scopus 4
РИНЦ 5
OpenAlex 4
Альметрики: