Microstructural Changes in La1−xCaxCoO3−δ Solid Solutions Under the Influence of Catalytic Reaction of Methane Combustion Научная публикация
Конференция |
EuropaCat-XII: 12th European Congress on Catalysis “Catalysis: Balancing the use of fossil and renewable resources” 30 авг. - 4 сент. 2015 , Казань |
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Журнал |
Topics in Catalysis
ISSN: 1022-5528 , E-ISSN: 1572-9028 |
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Вых. Данные | Год: 2016, Том: 59, Номер: 15-16, Страницы: 1354-1360 Страниц : 7 DOI: 10.1007/s11244-016-0661-4 | ||||||||
Ключевые слова | HRTEM, Oxidation, Perovskite, Planar defects, XRD | ||||||||
Авторы |
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Организации |
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Информация о финансировании (2)
1 | Российский научный фонд | 14-23-00037 |
2 | European Commission | 295180 FP7-PEOPLE-2011-IRSES |
Реферат:
Degradation of the surface of solid solutions La1−xCaxCoO3−δ (0.4 ≥ x ≥ 0) synthesized by the Pechini method was observed after catalytic oxidation of methane. According to XRD analysis, after the catalytic oxidation of CH4, the crystal structure of the samples did not change significantly, but HRTEM indicated the formation of nanoheterogeneities on the surface of the perovskite phase. Planar defects are formed in the direction of the crystallographic planes (111). Under the action of the reaction medium, areas with alternating layers having the perovskite and brownmillerite structure appeared in La0.6Ca0.4CoO3−δ.
Библиографическая ссылка:
Gerasimov E.
, Kulikovskaya N.
, Chuvilin A.
, Isupova L.
, Tsybulya S.
Microstructural Changes in La1−xCaxCoO3−δ Solid Solutions Under the Influence of Catalytic Reaction of Methane Combustion
Topics in Catalysis. 2016. V.59. N15-16. P.1354-1360. DOI: 10.1007/s11244-016-0661-4 WOS Scopus РИНЦ CAPlusCA OpenAlex
Microstructural Changes in La1−xCaxCoO3−δ Solid Solutions Under the Influence of Catalytic Reaction of Methane Combustion
Topics in Catalysis. 2016. V.59. N15-16. P.1354-1360. DOI: 10.1007/s11244-016-0661-4 WOS Scopus РИНЦ CAPlusCA OpenAlex
Даты:
Опубликована online: | 18 июл. 2016 г. |
Опубликована в печати: | 1 сент. 2016 г. |
Идентификаторы БД:
Web of science: | WOS:000382849100010 |
Scopus: | 2-s2.0-84984920632 |
РИНЦ: | 26872825 |
Chemical Abstracts: | 2016:1194814 |
Chemical Abstracts (print): | 165:304571 |
OpenAlex: | W2505336844 |