Random Distribution of EFG Parameters in 27Al MAS NMR Spectra of AlOx/SiO2 Catalysts and Related Systems | Sciact - CRIS-система Института катализа

Random Distribution of EFG Parameters in 27Al MAS NMR Spectra of AlOx/SiO2 Catalysts and Related Systems Научная публикация

Журнал

Applied Magnetic Resonance
ISSN: 0937-9347 , E-ISSN: 1613-7507

Вых. Данные

Год: 2016, Том: 47, Номер: 11, Страницы: 1193-1205 Страниц : 13 DOI: 10.1007/s00723-016-0837-x

Ключевые слова

Alumina; Aluminum; Catalysts; Magic angle spinning; Nuclear magnetic resonance spectroscopy

Авторы

Shubin Aleksandr A. ^1,2 , Terskikh Victor V. ³ , Papulovskiy Evgeniy ^1,2 , Lapina Olga B. ^1,2

Организации

1	Boreskov Institute of Catalysis, pr. Lavrentieva, 5, Novosibirsk 630090, Russia
2	Novosibirsk State University, Pirogova, 2, Novosibirsk 630090, Russia
3	Department of Chemistry, University of Ottawa, Ottawa, ON K1N6N5, Canada

Информация о финансировании (1)

Российский научный фонд

14-23-00037

27Al magic angle spinning (MAS) nuclear amgnetic resonance (NMR) spectroscopy is one of the primary tools in the structural characterization of a variety of alumina-based catalysts. However, the controversy still exists on the proper interpretation of 27Al NMR spectra due to difficulties associated with distribution of NMR parameters and by the experimental limitations. In this work, we present analysis of the 27Al MAS NMR spectra containing signals from Al(4), Al(5) and Al(6) species on the surface of AlOx/SiO2 catalysts and demonstrate several characteristic tell-tale properties of these signals caused by the random distribution of the EFG tensor parameters and by the partial excitation of NMR spectra.

Shubin A.A. , Terskikh V.V. , Papulovskiy E. , Lapina O.B.
Random Distribution of EFG Parameters in 27Al MAS NMR Spectra of AlOx/SiO2 Catalysts and Related Systems
Applied Magnetic Resonance. 2016. V.47. N11. P.1193-1205. DOI: 10.1007/s00723-016-0837-x WOS Scopus РИНЦ CAPlusCA OpenAlex

Поступила в редакцию:	3 авг. 2016 г.
Опубликована online:	21 сент. 2016 г.
Опубликована в печати:	1 нояб. 2016 г.

Web of science:	WOS:000386694200003
Scopus:	2-s2.0-84988664619
РИНЦ:	27573607
Chemical Abstracts:	2016:1553171
Chemical Abstracts (print):	170:74057
OpenAlex:	W2521527290

БД	Цитирований
Web of science	1
Scopus	2
РИНЦ	2
OpenAlex	2