Support Effect for Nanosized Au Catalysts in Hydrogen Production from Formic Acid Decomposition | Sciact - CRIS-system of Boreskov Institute of Catalysis

Support Effect for Nanosized Au Catalysts in Hydrogen Production from Formic Acid Decomposition Full article

Journal

Catalysis Science and Technology
ISSN: 2044-4753 , E-ISSN: 2044-4761

Output data

Year: 2016, Volume: 6, Number: 18, Pages: 6853-6860 Pages count : 8 DOI: 10.1039/C6CY00552G

Tags

Catalyst activity; Catalysts; Chemical bonds; Electronegativity; Formic acid; Gold; Hydrogen production; Reaction intermediates

Authors

Zacharska Monika ^1,2 , Chuvilin Andrey L. ^3,4 , Kriventsov Vladimir V. ⁵ , Beloshapkin Sergey ² , Estrada Miguel ⁶ , Simakov Andrey ⁶ , Bulushev Dmitri A. ^5,7,8

Affiliations

1	Chemical & Environmental Sciences Department, University of Limerick, Limerick, Ireland
2	Materials & Surface Science Institute, University of Limerick, Limerick, Ireland
3	CIC nanoGUNE Consolider, Donostia - San Sebastián, 20018 Spain
4	IKERBASQUE, Basque Foundation for Science, Bilbao, 20013 Spain
5	Boreskov Institute of Catalysis, SB RAS, Novosibirsk 630090, Russia
6	Centro de Nanociencias y Nanotecnología de la UNAM, Ensenada, México
7	Novosibirsk State University, Novosibirsk 630090, Russia
8	Nikolaev Institute of Inorganic Chemistry, SB RAS, Novosibirsk 630090, Russia

Funding (8)

1	Russian Foundation for Basic Research	16-03-01139
2	Russian Foundation for Basic Research	14-03-01066
3	Russian Science Foundation	16-13-00016
4	European Commission	295180 FP7-PEOPLE-2011-IRSES
5	National Autonomous University of Mexico National Council of Science and Technology	179619
6	National Autonomous University of Mexico	203813
7	European Commission
8	FEI Company

Catalysts with about 2.5 wt% of gold supported on Al2O3, ZrO2, CeO2, La2O3 and MgO oxides and with the same mean metal particle sizes of 2.4–3.0 nm have been studied in hydrogen production via formic acid decomposition. A strong volcano-type relation of the catalytic activity on the electronegativity of the support's cation was demonstrated with the Au/Al2O3 catalyst on the top. This indicated that the activity is affected by the acid–base properties of the support. A study of the most active Au/Al2O3 catalyst with aberration-corrected HAADF/STEM, XPS and EXAFS proved that gold is in metallic state. The content of single supported gold atoms/cations was negligible. Therefore, the mechanism of the reaction was related to the activation of formic acid on the catalyst's support followed by further decomposition of the formed reaction intermediate on the Au/support interface.

Zacharska M. , Chuvilin A.L. , Kriventsov V.V. , Beloshapkin S. , Estrada M. , Simakov A. , Bulushev D.A.
Support Effect for Nanosized Au Catalysts in Hydrogen Production from Formic Acid Decomposition

Catalysis Science and Technology. 2016. V.6. N18. P.6853-6860. DOI: 10.1039/C6CY00552G WOS Scopus РИНЦ ANCAN OpenAlex

Full text from publisher

Submitted:	Mar 12, 2016
Accepted:	May 6, 2016
Published online:	May 9, 2016

Web of science:	WOS:000384241800011
Scopus:	2-s2.0-84987680666
Elibrary:	27576272
Chemical Abstracts:	2016:744035
Chemical Abstracts (print):	165:331620
OpenAlex:	W2347012234

DB	Citing
Web of science	56
Scopus	59
Elibrary	56
OpenAlex	59