An X-Ray Photoelectron Spectroscopy and Quantum Chemical Study of Copper(II) β-Diketonates and Cu(HFA)2 Complexes with Imidazoline Ligands Научная публикация
| Журнал |
Journal of Electron Spectroscopy and Related Phenomena
ISSN: 0368-2048 , E-ISSN: 1873-2526 |
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| Вых. Данные | Год: 2016, Том: 212, Страницы: 11-20 Страниц : 10 DOI: 10.1016/j.elspec.2016.06.005 | ||||||||
| Ключевые слова | Complexes with nitroxyl radicals, DFT method, X-ray photoelectron spectroscopy, Сu(II) β-diketonates | ||||||||
| Авторы |
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| Организации |
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Информация о финансировании (1)
| 1 | Российская академия наук | V.44.4.4. |
Реферат:
An X-ray photoelectron spectroscopy study of the charge and spin state of copper(II) -diketonates and Cu(hfa)2 (hfa–hexafluoroacetylacetonate) complexes with imidazoline ligands is performed with comparison to the data of quantum chemical calculations. It is shown that the structure of the spectra of copper is described by a superposition of the |2p53d9> and | 2p53d10L> electronic states determined by electron transfer processes between copper and L ligand atoms. It is found that during the coordination of imidazoline ligands to the Cu(hfa)2 complex the spin density is redistributed through the chain of chemical bonds from the ligand nitroxyl group to the copper atom.
Библиографическая ссылка:
Kryuchkova N.A.
, Stabnikov P.A.
, Kalinkin A.V.
, Fursova E.Y.
An X-Ray Photoelectron Spectroscopy and Quantum Chemical Study of Copper(II) β-Diketonates and Cu(HFA)2 Complexes with Imidazoline Ligands
Journal of Electron Spectroscopy and Related Phenomena. 2016. V.212. P.11-20. DOI: 10.1016/j.elspec.2016.06.005 WOS Scopus РИНЦ OpenAlex CAPlus
An X-Ray Photoelectron Spectroscopy and Quantum Chemical Study of Copper(II) β-Diketonates and Cu(HFA)2 Complexes with Imidazoline Ligands
Journal of Electron Spectroscopy and Related Phenomena. 2016. V.212. P.11-20. DOI: 10.1016/j.elspec.2016.06.005 WOS Scopus РИНЦ OpenAlex CAPlus
Даты:
| Поступила в редакцию: | 18 апр. 2016 г. |
| Принята к публикации: | 2 июл. 2016 г. |
| Опубликована online: | 27 июл. 2016 г. |
| Опубликована в печати: | 1 окт. 2016 г. |
Идентификаторы БД:
| ≡ Web of science: | WOS:000387191800003 |
| ≡ Scopus: | 2-s2.0-84979516755 |
| ≡ РИНЦ: | 27095109 |
| ≡ OpenAlex: | W2491398368 |
| ≡ Chemical Abstracts: | 2016:1252714 |