Thermal Stability of Ag–Au, Cu–Au, and Ag–Cu Bimetallic Nanoparticles Supported on Highly Oriented Pyrolytic Graphite Full article
| Journal |
Kinetics and Catalysis
ISSN: 0023-1584 , E-ISSN: 1608-3210 |
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| Output data | Year: 2016, Volume: 57, Number: 5, Pages: 704-711 Pages count : 8 DOI: 10.1134/S0023158416050049 | ||
| Tags | bimetallic catalysts, highly oriented pyrolytic graphite, thermal stability, X-ray photoelectron spectroscopy | ||
| Authors |
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| Affiliations |
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Funding (1)
| 1 | Russian Science Foundation | 14-23-00146 |
Abstract:
he formation of Ag–Au, Cu–Au, and Ag–Cu bimetallic particles on the surface of highly oriented pyrolytic graphite was studied by X-ray photoelectron spectroscopy. Samples with the core–shell structure of particles were prepared by sequential thermal vacuum deposition. The thermal stability of the samples was studied over a wide range of temperatures (25-400°C) under ultrahigh-vacuum conditions. The heating of the samples to ~250°C leads to the formation of bimetallic alloy particles with a relatively uniform distribution of metals in the bulk. The thermal stability of the samples with respect to sintering depends on the nature of the supported metals. Thus, the Ag–Au particles exhibited the highest thermal resistance (~350°C) under ultrahigh-vacuum conditions, whereas the Ag–Cu particles agglomerated even at ~250°C.
Cite:
Bukhtiyarov A.V.
, Prosvirin I.P.
, Chetyrin I.A.
, Saraev A.A.
, Kaichev V.V.
, Bukhtiyarov V.I.
Thermal Stability of Ag–Au, Cu–Au, and Ag–Cu Bimetallic Nanoparticles Supported on Highly Oriented Pyrolytic Graphite
Kinetics and Catalysis. 2016. V.57. N5. P.704-711. DOI: 10.1134/S0023158416050049 WOS Scopus РИНЦ AN OpenAlex
Thermal Stability of Ag–Au, Cu–Au, and Ag–Cu Bimetallic Nanoparticles Supported on Highly Oriented Pyrolytic Graphite
Kinetics and Catalysis. 2016. V.57. N5. P.704-711. DOI: 10.1134/S0023158416050049 WOS Scopus РИНЦ AN OpenAlex
Original:
Бухтияров А.В.
, Просвирин И.П.
, Четырин И.А.
, Сараев А.А.
, Каичев В.В.
, Бухтияров В.И.
Термическая стабильность биметаллических наночастиц Ag–Au, Cu–Au и Ag–Cu, нанесенных на высокоориентированный пиролитический графит
Кинетика и катализ. 2016. Т.57. №5. С.711-718. DOI: 10.7868/S045388111605004X РИНЦ OpenAlex
Термическая стабильность биметаллических наночастиц Ag–Au, Cu–Au и Ag–Cu, нанесенных на высокоориентированный пиролитический графит
Кинетика и катализ. 2016. Т.57. №5. С.711-718. DOI: 10.7868/S045388111605004X РИНЦ OpenAlex
Dates:
| Submitted: | Feb 17, 2016 |
| Published print: | Sep 1, 2016 |
| Published online: | Oct 12, 2016 |
Identifiers:
| Web of science: | WOS:000386165000016 |
| Scopus: | 2-s2.0-84991106737 |
| Elibrary: | 27575167 |
| Chemical Abstracts: | 2016:1654971 |
| OpenAlex: | W2530721494 |