Catalytic Oxidation of α-alkenes with Hydrogen Peroxide to Carboxylic Acids in the Presence of Peroxopolyoxotungstate Complexes Научная публикация
| Журнал |
Catalysis Communications
ISSN: 1566-7367 , E-ISSN: 1873-3905 |
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| Вых. Данные | Год: 2017, Том: 88, Страницы: 45-49 Страниц : 5 DOI: 10.1016/j.catcom.2016.09.019 | ||
| Ключевые слова | Alpha-alkenes, Carboxylic acids, Peroxotungstate complexes, Phase-transfer catalysis, Quaternary ammonium cations | ||
| Авторы |
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| Организации |
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Информация о финансировании (2)
| 1 | Федеральное агентство научных организаций России | V.44.2.8. |
| 2 | Российский фонд фундаментальных исследований | 16-03-00127 |
Реферат:
Fine organic synthesis investigation has been performed, focusing on the possibility of efficient oxidation of α-alkenes by hydrogen peroxide under conditions of phase transfer catalysis using bifunctional metal complex catalysts based on peroxotungsten compounds of general formula Q3{PO4[WO(O2)2]4}, where Q is organic cation containing quaternary nitrogen atom.
Catalysts screening has been done at oxidation of octene-1, decene-1 and dodecene-1 by 30% aqueous hydrogen peroxide to obtain carboxylic acids: heptanoic, nonanoic and undecanoic acids being of importance since used as precursors in the synthesis of various organic and biologically active compounds. This approach to the synthesis of carboxylic acids may be of interest for the processes of “green chemistry” occurring under mild conditions (Т < 100 °С, Р – atm) in one stage without organic solvents, and providing high target product yields (86–97%).
Библиографическая ссылка:
Pai Z.P.
, Selivanova N.V.
, Oleneva P.V.
, Berdnikova P.V.
, Beskopyl'nyi A.M.
Catalytic Oxidation of α-alkenes with Hydrogen Peroxide to Carboxylic Acids in the Presence of Peroxopolyoxotungstate Complexes
Catalysis Communications. 2017. V.88. P.45-49. DOI: 10.1016/j.catcom.2016.09.019 WOS Scopus РИНЦ CAPlusCA OpenAlex
Catalytic Oxidation of α-alkenes with Hydrogen Peroxide to Carboxylic Acids in the Presence of Peroxopolyoxotungstate Complexes
Catalysis Communications. 2017. V.88. P.45-49. DOI: 10.1016/j.catcom.2016.09.019 WOS Scopus РИНЦ CAPlusCA OpenAlex
Даты:
| Поступила в редакцию: | 20 июл. 2016 г. |
| Принята к публикации: | 14 сент. 2016 г. |
| Опубликована online: | 15 сент. 2016 г. |
| Опубликована в печати: | 1 янв. 2017 г. |
Идентификаторы БД:
| Web of science: | WOS:000389117500011 |
| Scopus: | 2-s2.0-84988662371 |
| РИНЦ: | 28273158 |
| Chemical Abstracts: | 2016:1585060 |
| Chemical Abstracts (print): | 165:487395 |
| OpenAlex: | W2518756491 |