Electrocatalysis of the Hydrogen Oxidation Reaction on Carbon-Supported Bimetallic NiCu Particles Prepared by an Improved Wet Chemical Synthesis | Sciact - CRIS-system of Boreskov Institute of Catalysis

Electrocatalysis of the Hydrogen Oxidation Reaction on Carbon-Supported Bimetallic NiCu Particles Prepared by an Improved Wet Chemical Synthesis Full article

Journal

Journal of Electroanalytical Chemistry
ISSN: 1572-6657

Output data

Year: 2016, Volume: 783, Pages: 146-151 Pages count : 6 DOI: 10.1016/j.jelechem.2016.11.031

Tags

Alkaline solutions, Copper, Hydrogen oxidation reaction, Lyophilization, Nickel

Authors

Cherstiouk Olga V. ^1,2 , Simonov Pavel A. ^1,2 , Oshchepkov Alexandr G. ^1,3,4 , Zaikovskii Vladimir I. ^1,2 , Kardash Tatyana Yu. ^1,2 , Bonnefont Antoine ³ , Parmon Valentin N. ^1,2 , Savinova Elena R. ³

Affiliations

1	Boreskov Institute of Catalysis, Novosibirsk 630090, Russia
2	Novosibirsk State University, Novosibirsk 630090, Russia
3	Institut de Chimie de Strasbourg, UMR 7177 CNRS-University of Strasbourg, 67070 Strasbourg, France
4	Institut de Chimie et Procédés pour l'Energie, l'Environnement et la Santé, UMR 7515 CNRS-University of Strasbourg, 67087 Strasbourg Cedex, France

Funding (1)

Federal Agency for Scientific Organizations

0303-2015-0007

Carbon supported Ni1 − xCux/C catalysts with different Ni:Cu atomic ratios comprising ca 30 nm particles uniformly distributed over the surface of carbon support were prepared by the incipient wetness impregnation followed by freeze-drying. The catalysts have been characterized by X-ray powder diffraction, transmission electron microscopy and cyclic voltammetry. The electrocatalytic activities of Ni1 − xCux/C catalysts in the hydrogen oxidation reaction in alkaline medium were examined with linear sweep voltammetry. It was found that addition of Cu at low fractions significantly improves the electrocatalytic activity of Ni in the hydrogen oxidation reaction, while increasing the Cu fraction above 5% results in its attenuation. The observed behavior of NiCu catalysts is compared to the literature data and tentatively explained by the influence of Cu on the energy of hydrogen adsorption on Ni.

Cherstiouk O.V. , Simonov P.A. , Oshchepkov A.G. , Zaikovskii V.I. , Kardash T.Y. , Bonnefont A. , Parmon V.N. , Savinova E.R.
Electrocatalysis of the Hydrogen Oxidation Reaction on Carbon-Supported Bimetallic NiCu Particles Prepared by an Improved Wet Chemical Synthesis
Journal of Electroanalytical Chemistry. 2016. V.783. P.146-151. DOI: 10.1016/j.jelechem.2016.11.031 WOS Scopus РИНЦ ANCAN OpenAlex

Submitted:	Aug 31, 2016
Accepted:	Nov 14, 2016
Published online:	Nov 16, 2016
Published print:	Dec 15, 2016

Web of science:	WOS:000390627500020
Scopus:	2-s2.0-85002340227
Elibrary:	29473440
Chemical Abstracts:	2016:1933851
Chemical Abstracts (print):	166:71220
OpenAlex:	W2551233518

DB	Citing
Web of science	67
Scopus	71
Elibrary	62
OpenAlex	78