Effect of Nitric Acid Modification of Montmorillonite Clay on Synthesis of Solketal from Glycerol and Acetone | Sciact - CRIS-система Института катализа

Effect of Nitric Acid Modification of Montmorillonite Clay on Synthesis of Solketal from Glycerol and Acetone Научная публикация

Журнал

Catalysis Communications
ISSN: 1566-7367 , E-ISSN: 1873-3905

Вых. Данные

Год: 2017, Том: 90, Страницы: 65-69 Страниц : 5 DOI: 10.1016/j.catcom.2016.11.020

Ключевые слова

Acetone, Acid activation, Glycerol, Montmorillonite, Solketal

Авторы

Timofeeva Maria N. ^1,2 , Panchenko Valentina N. ^1,2 , Krupskaya Victoria V. ^3,4 , Gil Antonio ⁵ , Vicente Miguel A. ⁶

Организации

1	Boreskov Institute of Catalysis SB RAS, Prospekt Akad. Lavrentieva 5, 630090 Novosibirsk, Russian Federation
2	Novosibirsk State University, st. Pirogova 2, 630090, Novosibirsk, Russian Federation
3	Institute of Geology of Ore Deposits, Petrography, Mineralogy and Geochemistry RAS, pr. Staromonetny 35, 119017 Moscow, Russian Federation
4	Moscow State University, Leninskie Gory 1, 119991, Moscow, Russian Federation
5	Department of Applied Chemistry, Public University of Navarra, 31006 Pamplona, Spain
6	Department of Inorganic Chemistry, University of Salamanca, Salamanca, Spain

Информация о финансировании (2)

1	Федеральное агентство научных организаций России	V.44.2.12.
2	Ministry of Economic Affairs and Digital Transformation	MAT2013-47811-C2-1-R, MAT2013-47811-C2-2-R

The effect of acid modification of a natural montmorillonite clay (MM) by HNO3 on the catalytic properties of MM from Dash-Salakhlinsk (Kazakhstan) has been investigated in the synthesis of solketal from glycerol and acetone in solvent free and acetonitrile media. HNO3 concentration allowed to control the chemical composition, the surface acidity, the porous structure of the acid-activated MMs and their catalytic performance. The main reaction product was solketal with 86.6-98% selectivity. Conversion of glycerol depended on the Brønsted acidity. The most active sample, namely MM activated with 0.5 mol/dm3 HNO3, showed good reusability for 3 catalyst cycles.

Timofeeva M.N. , Panchenko V.N. , Krupskaya V.V. , Gil A. , Vicente M.A.
Effect of Nitric Acid Modification of Montmorillonite Clay on Synthesis of Solketal from Glycerol and Acetone
Catalysis Communications. 2017. V.90. P.65-69. DOI: 10.1016/j.catcom.2016.11.020 WOS Scopus РИНЦ CAPlusCA OpenAlex

Поступила в редакцию:	1 авг. 2016 г.
Принята к публикации:	11 нояб. 2016 г.
Опубликована online:	23 нояб. 2016 г.
Опубликована в печати:	1 февр. 2017 г.

Web of science:	WOS:000392039000016
Scopus:	2-s2.0-85003485961
РИНЦ:	29472613
Chemical Abstracts:	2016:1985974
Chemical Abstracts (print):	166:41224
OpenAlex:	W2550249273

БД	Цитирований
Web of science	64
Scopus	70
РИНЦ	71
OpenAlex	74