Metal Dusting as a Route to Produce Active Catalyst for Processing Chlorinated Hydrocarbons into Carbon Nanomaterials Full article
| Conference |
IX International Conference “Mechanisms of Catalytic Reactions” 22-25 Oct 2012 , Санкт-Петербург |
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| Journal |
Topics in Catalysis
ISSN: 1022-5528 , E-ISSN: 1572-9028 |
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| Output data | Year: 2013, Volume: 56, Number: 11, Pages: 1026-1032 Pages count : 7 DOI: 10.1007/s11244-013-0066-6 | ||||||
| Tags | 1,2-dichloroethane, Bulk metals and alloys, Carbon nanofibers, Chlorinated hydrocarbons, Metal dusting, NiCr alloy | ||||||
| Authors |
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| Affiliations |
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Funding (2)
| 1 | Russian Foundation for Basic Research | 12-03-31729 |
| 2 | Президиум РАН | 5.2.2 |
Abstract:
The interaction of 1,2-dichloroethane (DCE) vapors with bulk NiCr alloy resulting in complete metal wastage with the formation of carbon nanofibers (CNFs) has been described from mechanistic point of view. The genesis of surface transformations of the bulk NiCr alloy exposed to corrosive reaction mix Ar/H2/DCE at 550 °C was studied by AFM, SEM and TEM techniques. The mechanism of metal dusting in aggressive reaction media was suggested. The observed process has been considered as a way to produce the self-organizing Ni/CNF catalyst which is effective for further decomposition of chlorinated hydrocarbons leading to nanostructured carbon product.
Cite:
Mishakov I.V.
, Bauman Y.I.
, Korneev D.V.
, Vedyagin A.A.
Metal Dusting as a Route to Produce Active Catalyst for Processing Chlorinated Hydrocarbons into Carbon Nanomaterials
Topics in Catalysis. 2013. V.56. N11. P.1026-1032. DOI: 10.1007/s11244-013-0066-6 WOS Scopus РИНЦ OpenAlex ANCAN
Metal Dusting as a Route to Produce Active Catalyst for Processing Chlorinated Hydrocarbons into Carbon Nanomaterials
Topics in Catalysis. 2013. V.56. N11. P.1026-1032. DOI: 10.1007/s11244-013-0066-6 WOS Scopus РИНЦ OpenAlex ANCAN
Dates:
| Published online: | May 24, 2013 |
| Published print: | Aug 1, 2013 |
Identifiers:
| ≡ Web of science: | WOS:000321664200019 |
| ≡ Scopus: | 2-s2.0-84880420077 |
| ≡ Elibrary: | 20443516 |
| ≡ OpenAlex: | W1963628298 |
| ≡ Chemical Abstracts: | 2013:851865 |
| ≡ Chemical Abstracts (print): | 159:136606 |