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Metal Dusting as a Route to Produce Active Catalyst for Processing Chlorinated Hydrocarbons into Carbon Nanomaterials Full article

Conference IX International Conference “Mechanisms of Catalytic Reactions”
22-25 Oct 2012 , Санкт-Петербург
Journal Topics in Catalysis
ISSN: 1022-5528 , E-ISSN: 1572-9028
Output data Year: 2013, Volume: 56, Number: 11, Pages: 1026-1032 Pages count : 7 DOI: 10.1007/s11244-013-0066-6
Tags 1,2-dichloroethane, Bulk metals and alloys, Carbon nanofibers, Chlorinated hydrocarbons, Metal dusting, NiCr alloy
Authors Mishakov Ilya V. 1,2 , Bauman Yurii I. 1 , Korneev Denis V. 3 , Vedyagin Aleksey A. 1,2
Affiliations
1 Boreskov Institute of Catalysis SB RAS, Novosibirsk, Russia
2 Novosibirsk State Technical University, Novosibirsk, Russia
3 State Research Center of Virology and Biotechnology ‘‘Vector’’, 630559 Koltsovo, Russia

Funding (2)

1 Russian Foundation for Basic Research 12-03-31729
2 Президиум РАН 5.2.2

Abstract: The interaction of 1,2-dichloroethane (DCE) vapors with bulk NiCr alloy resulting in complete metal wastage with the formation of carbon nanofibers (CNFs) has been described from mechanistic point of view. The genesis of surface transformations of the bulk NiCr alloy exposed to corrosive reaction mix Ar/H2/DCE at 550 °C was studied by AFM, SEM and TEM techniques. The mechanism of metal dusting in aggressive reaction media was suggested. The observed process has been considered as a way to produce the self-organizing Ni/CNF catalyst which is effective for further decomposition of chlorinated hydrocarbons leading to nanostructured carbon product.
Cite: Mishakov I.V. , Bauman Y.I. , Korneev D.V. , Vedyagin A.A.
Metal Dusting as a Route to Produce Active Catalyst for Processing Chlorinated Hydrocarbons into Carbon Nanomaterials
Topics in Catalysis. 2013. V.56. N11. P.1026-1032. DOI: 10.1007/s11244-013-0066-6 WOS Scopus РИНЦ ANCAN OpenAlex
Dates:
Published online: May 24, 2013
Published print: Aug 1, 2013
Identifiers:
Web of science: WOS:000321664200019
Scopus: 2-s2.0-84880420077
Elibrary: 20443516
Chemical Abstracts: 2013:851865
Chemical Abstracts (print): 159:136606
OpenAlex: W1963628298
Citing:
DB Citing
Web of science 33
Scopus 36
Elibrary 41
OpenAlex 37
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