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Optimization of Adsorption Dynamics in Adsorptive Chillers: Loose Grains Configuration Full article

Journal Energy
ISSN: 0360-5442 , E-ISSN: 1873-6785
Output data Year: 2012, Volume: 46, Pages: 484-492 Pages count : 9 DOI: 10.1016/j.energy.2012.08.001
Tags Adsorption chillers, Adsorption dynamics, Dynamic optimization, Heat and mass transfer, Large temperature jump method, Silica gel-water pair
Authors Aristov Yu.I. 1 , Glaznev Ivan S. 1 , Girnik Ilya S. 1,2
Affiliations
1 Boreskov Institute of Catalysis, Pr. Lavrentieva 5, 630090 Novosibirsk, Russian Federation
2 Novosibirsk State University, Pirogova st, 2, 630090 Novosibirsk, Russian Federation

Funding (1)

1 Russian Foundation for Basic Research 10-08-91156

Abstract: Dynamic performance of adsorption chillers (ACs) with adsorbent beds of loose grains is addressed in this paper. Temporal evolution of quasi-isobaric ad-/desorption curves for simple bed configuration of n-layers of loose grains (n = 1, 2, 4, and 8) located on a heat transfer metal support is studied. The support is subjected to fast temperature drop (50 °C → 30 °C) or jump (58 °C → 80 °C) typical for AC cycles. The size d of Fuji silica RD grains is varied from 0.2 to 1.8 mm. At n = 1–4, the experimental kinetic curves are nearly exponential, so that the major part of water ad-/desorption process can be described by a single characteristic time. It is found that the dynamics is invariant with respect to the ratio (S/m) = “heat transfer surface”/“adsorbent mass” which can be used for assessing the degree of dynamic perfection of an “adsorbent bed – heat exchanger” (Ad–HEx) unit. For small grains (d < 0.5–0.8 mm) and (S/m) ≥ 2 m2/kg, the “grain size insensitive” regime is established, for which loose silica grains of different size result in the same dynamic performance if the ratio (S/m) is constant. The “grain size sensitive” regime is realized for large adsorbent grains (d ≥ 0.8 mm): the specific power reduces with increasing the grain size. Practical recommendations on proper organization of the Ad–HEx unit as well as of the AC cycle durations are made. Analysis of the dynamic performance of four selected AC prototypes described in literature shows that their cycle powers are 2–6 times lower than those measured in our LTJ (Large Temperature Jump) tests. We discuss this difference as caused by several imperfections and pitfalls of either hardware or process organization rather than by poor adsorbent properties.
Cite: Aristov Y.I. , Glaznev I.S. , Girnik I.S.
Optimization of Adsorption Dynamics in Adsorptive Chillers: Loose Grains Configuration
Energy. 2012. V.46. P.484-492. DOI: 10.1016/j.energy.2012.08.001 WOS Scopus РИНЦ ANCAN OpenAlex
Dates:
Submitted: Feb 24, 2012
Accepted: Aug 2, 2012
Published online: Sep 6, 2012
Published print: Oct 1, 2012
Identifiers:
Web of science: WOS:000311873700051
Scopus: 2-s2.0-84867229434
Elibrary: 20491082
Chemical Abstracts: 2012:1474769
Chemical Abstracts (print): 158:305421
OpenAlex: W2002741951
Citing:
DB Citing
Web of science 128
Scopus 135
Elibrary 128
OpenAlex 146
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