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Separation of Phenol-Containing Pyrolysis Products Using Comprehensive Two-Dimensional Chromatography with Columns Based on Pyridinium Ionic Liquids Full article

Journal Journal of Analytical & Bioanalytical Techniques
ISSN: 2155-9872
Output data Year: 2016, Volume: 7, Article number : 313, Pages count : 5 DOI: 10.4172/2155-9872.1000313
Tags Comprehensive two-dimensional chromatography, Ionic liquids, High polar stationary phases, Bio-oil
Authors Shashkov Mikhail V 1 , Sidelnikov Vladimir N 2
Affiliations
1 Boreskov Institute of Catalysis SB RAS, Novosibirsk, Russian Federation
2 Novosibirsk State University, Novosibirsk, Russian Federation

Abstract: The work describes the application of columns with high-polar stationary liquid phases based on pyridinium ionic liquids for GC × GC separation of bio-oil and product of coal pyrolysis. By using inverse combination columns- the first ionic liquid column, the second is HP-5 the good separation results have been obtained. In the analysis of coal pyrolysis products, the suggested approach provides a much better resolution between components in comparison with a less polar first-dimension column (ZB-WAX). The good selectivity for peaks of phenols is observed, and the group of phenols is well detached and separated from the group of diaromatics. For bio-oil also good separation picture was obtained, the groups of phenols and guaiacol derivatives are distinguished with good resolution of substances within each group.
Cite: Shashkov M.V. , Sidelnikov V.N.
Separation of Phenol-Containing Pyrolysis Products Using Comprehensive Two-Dimensional Chromatography with Columns Based on Pyridinium Ionic Liquids
Journal of Analytical & Bioanalytical Techniques. 2016. V.7. 313 :1-5. DOI: 10.4172/2155-9872.1000313 РИНЦ AN OpenAlex
Files: Full text from publisher
Dates:
Submitted: Mar 9, 2016
Accepted: Mar 28, 2016
Published online: Apr 4, 2016
Identifiers:
Elibrary: 35006646
Chemical Abstracts: 2018:807609
OpenAlex: W2516392142
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