Sciact
  • EN
  • RU

Dispersed Complex Phosphates as Tailored Acid Catalysts: Synthesis and Properties Full article

Conference 1997 MRS Fall Meeting
01-05 Dec 1997 , Boston
Source Recent Advances in Catalytic Materials: Volume 497 (MRS Proceedings) 1st Edition
Compilation, Cambridge University Press; 1st edition (October 15, 1998). 1998. 270 c. ISBN 1558994025. РИНЦ
Journal MRS Online Proceedings Library
ISSN: 1946-4274
Output data Year: 1997, Volume: 497, Pages: 201-206 Pages count : 7 DOI: 10.1557/PROC-497-201
Tags Acidity; Acids; Amorphous materials; Catalyst activity; Catalysts; Composition; Crystalline materials; Dispersions; Hydrocarbons; Reduction; Surface structure; Synthesis (chemical)
Authors Sadykov Vladislav A. 1 , Kochubey D.I. 1 , Degtyarev S.P. 1 , Paukshtis E.A. 1 , Burgina E.B. 1 , Pavlova S.N. 1 , Maksimovskaya R.I. 1 , Litvak G.S. 1 , Zaikovskii V.I. 1 , Tsybulya S.V. 1 , Tretyakov V.F. 2 , Agrawal D. 3 , Roy R. 3
Affiliations
1 Boreskov Institute of Catalysis SD RAS, Novosibirsk, Russia, 630090
2 Topchiev Institute of Petrochemical Synthesis RAS, Moscow, Russia
3 Materials Research Lab, University Park, PA

Abstract: The relationship between the chemical composition, bulk real structure, surface properties and catalytic activity of dispersed complex framework zirconium phosphates with a NASICON-type structure is considered. For both crystalline and amorphous samples, a model of their bulk structure is suggested. The Lewis and Bröensted acidity was shown to vary broadly and be dependent upon the composition and preparation procedure, which is important for catalysts of hydro-carbons activation. Selective catalytic reduction of NOx by methane in excess oxygen appears to be one of the application areas for these systems.
Cite: Sadykov V.A. , Kochubey D.I. , Degtyarev S.P. , Paukshtis E.A. , Burgina E.B. , Pavlova S.N. , Maksimovskaya R.I. , Litvak G.S. , Zaikovskii V.I. , Tsybulya S.V. , Tretyakov V.F. , Agrawal D. , Roy R.
Dispersed Complex Phosphates as Tailored Acid Catalysts: Synthesis and Properties
In compilation Recent Advances in Catalytic Materials: Volume 497 (MRS Proceedings) 1st Edition. – Cambridge University Press; 1st edition (October 15, 1998)., 1997. – C.201-206. – ISBN 1558994025. DOI: 10.1557/PROC-497-201 WOS Scopus РИНЦ РИНЦ ANCAN OpenAlex
Dates:
Published print: Jan 1, 1997
Published online: Feb 10, 2011
Identifiers:
Web of science: WOS:000077031400028
Scopus: 2-s2.0-0032292958
Elibrary: 21461814 | 21928266
Chemical Abstracts: 1998:710055
Chemical Abstracts (print): 130:28664
OpenAlex: W2103408098
Citing:
DB Citing
Scopus 2
Elibrary 1
Altmetrics: