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Epoxidation of Oleic Acid Catalyzed by Peroxo Phosphotungstate in a Two-Phase System Full article

Journal Journal of Molecular Catalysis A: Chemical
ISSN: 1381-1169
Output data Year: 1998, Volume: 134, Number: 1-3, Pages: 223-228 Pages count : 6 DOI: 10.1016/S1381-1169(98)00039-9
Tags Epoxidation, Oleic acid, Polyoxometalates
Authors Kozhevnikov I.V. 1 , Mulder G.P. 2 , Steverink-de Zoete M.C. 2 , Oostwalb M.G. 2
Affiliations
1 Leverhulme Ctr. for Innovative Catalysis, Department of Chemistry, University of Liverpool
2 Unichema International, Buurtje 1, PO Box 2, Netherlands

Funding (1)

1 Unichema International

Abstract: The peroxo phosphotungstate {PO4[WO(O2)2]4}3− is a highly efficient catalyst (or catalyst precursor) for the phase-transfer epoxidation of oleic acid by aqueous 35–60% hydrogen peroxide, yielding 84% epoxide (based on oleic acid) at 95% oleic acid conversion and 800–1200 catalyst turnovers, without using a chlorocarbon solvent.
Cite: Kozhevnikov I.V. , Mulder G.P. , Steverink-de Zoete M.C. , Oostwalb M.G.
Epoxidation of Oleic Acid Catalyzed by Peroxo Phosphotungstate in a Two-Phase System
Journal of Molecular Catalysis A: Chemical. 1998. V.134. N1-3. P.223-228. DOI: 10.1016/S1381-1169(98)00039-9 WOS Scopus РИНЦ ANCAN OpenAlex
Dates:
Submitted: Aug 26, 1997
Accepted: Sep 22, 1997
Published print: Sep 15, 1998
Published online: Jan 6, 1999
Identifiers:
Web of science: WOS:000075960100020
Scopus: 2-s2.0-0032530509
Elibrary: 22010468
Chemical Abstracts: 1998:533798
Chemical Abstracts (print): 130:3478
OpenAlex: W2088460214
Citing:
DB Citing
Web of science 53
Scopus 55
Elibrary 44
OpenAlex 58
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